ChemicalBook Product Catalog Organic Chemistry Phosphines TRIS(4-CHLOROPHENYL)PHOSPHINE

TRIS(4-CHLOROPHENYL)PHOSPHINE

TRIS(4-CHLOROPHENYL)PHOSPHINE Basic information
Product Name:TRIS(4-CHLOROPHENYL)PHOSPHINE
Synonyms:Tri(p-chlorophenyl)phosphine,99%;TRIS(P-CHLOROPHENYL)PHOSPHINE;TRIS(4-CHLOROPHENYL)PHOSPHINE;TRI(P-CHLOROPHENYL)PHOSPHINE;TRI(4-CHLOROPHENYL)PHOSPHINE;Phosphine, tris(4-chlorophenyl)-;Phosphine, tris(p-chlorophenyl)-;1,1-dimethyl-3-(5-nitro-1,2-benzothiazol-3-yl)urea
CAS:1159-54-2
MF:C18H12Cl3P
MW:365.62
EINECS:214-596-7
Product Categories:Achiral Phosphine;Aryl Phosphine;Ligand;Basic Phosphine LigandsCatalysis and Inorganic Chemistry;Catalysis and Inorganic Chemistry;organophosphorus ligand;Cross-Coupling;Phosphine Ligands;Phosphorus Compounds
Mol File:1159-54-2.mol
TRIS(4-CHLOROPHENYL)PHOSPHINE Structure
TRIS(4-CHLOROPHENYL)PHOSPHINE Chemical Properties
Melting point 100-103 °C (lit.)
Boiling point 427.6±40.0 °C(Predicted)
storage temp. Inert atmosphere,Room Temperature
form crystal
color white
Sensitive Air Sensitive
BRN 751458
CAS DataBase Reference1159-54-2(CAS DataBase Reference)
Safety Information
Hazard Codes Xi
Risk Statements 36/37/38
Safety Statements 26-37/39
RIDADR 3278
WGK Germany 3
TSCA No
PackingGroup III
HS Code 29310099
MSDS Information
ProviderLanguage
ACROS English
SigmaAldrich English
ALFA English
TRIS(4-CHLOROPHENYL)PHOSPHINE Usage And Synthesis
Chemical Propertieswhite to light yellow crystal powde
UsesCatalyst for:
  • Preparation of chromans and (E,E)-1,3-dienes via reaction of γ-substituted allenoates with aldehydes
  • Solvent-free Heck reactions

Cocatalyst in:
  • Regioselective carbomagnesiation of terminal alkynes and enynes with alkyl Grignard reagents
  • Rhodium-catalyzed coordination-assisted regioselective alkenylation of aromatic C-H bonds with terminal silylacetylenes
  • Rhodium-catalyzed hydrogenation reactions
  • Platinum-catalyzed allylation reactions
TRIS(4-CHLOROPHENYL)PHOSPHINE Preparation Products And Raw materials
TRIS(4-FORMYLPHENYL)AMINE Tris(4-fluorophenyl)phosphine TRIS(4-TRIFLUOROMETHYLPHENYL)PHOSPHINE TRIS(4-HYDROXYPHENYL)PHOSPHINE OXIDE 4,4',4''-TRICHLOROTRITYL ALCOHOL TRIS-(4-AMINOPHENYL)THIOPHOSPHATE Tris(4-isocyanatophenyl) thiophosphate Tris(4-fluorophenyl)phosphine Tris(4-bromophenyl)amine TRIS(4-CHLOROPHENYL)PHOSPHINE TRIS(4-CHLOROPHENYL)(METHYL)PHOSPHONIUM IODIDE TRIS(4-CHLOROPHENYL)PHOSPHINE OXIDE TRIS(4-CHLOROPHENYL)(2,3,4,5,6-PENTAMETHYLBENZYL)PHOSPHONIUM CHLORIDE TRIS(3-CHLOROPHENYL)PHOSPHINE Tri(4-chlorophenyl)phosphine oxide Bis(tris(p-chlorophenyl)phosphine)mercuric chloride complex Phosphine
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