Benzophenone oxime

Benzophenone oxime Basic information
Product Name:Benzophenone oxime
Synonyms:Benzophenonoxim;Benzophenoxime;Diphenyl ketoxime;diphenylketoxime;diphenylmethanoneoxime;Diphenyl-methanoneoxime;diphenyl-methanonoxime;Methanone,diphenyl-,oxime
CAS:574-66-3
MF:C13H11NO
MW:197.23
EINECS:209-373-6
Product Categories:Aromatic Hydrazides, Hydrazines, Hydrazones and Oximes;bc0001
Mol File:574-66-3.mol
Benzophenone oxime Structure
Benzophenone oxime Chemical Properties
Melting point 140-144 °C
Boiling point 334.34°C (rough estimate)
density 1.0957 (rough estimate)
refractive index 1.6050 (estimate)
storage temp. Inert atmosphere,2-8°C
form Powder
pka10.90±0.70(Predicted)
color White
Water Solubility insoluble
Sensitive Air & Moisture Sensitive
Merck 14,1098
BRN 1869643
CAS DataBase Reference574-66-3(CAS DataBase Reference)
NIST Chemistry ReferenceMethanone, diphenyl-, oxime(574-66-3)
EPA Substance Registry SystemMethanone, diphenyl-, oxime (574-66-3)
Safety Information
Hazard Codes Xi,Xn
Risk Statements 36/37/38-20/21/22
Safety Statements 37/39-26-36
RTECS DJ1810000
TSCA Yes
HS Code 29280000
ToxicityLD50 unr-mus: 560 mg/kg PCJOAU 12,227,78
MSDS Information
ProviderLanguage
Benzophenone oxime English
ACROS English
ALFA English
Benzophenone oxime Usage And Synthesis
Chemical Propertieswhite powder
Safety ProfileModerately toxic by unspecifiedroute. When heated to decomposition it emits toxicvapors of NOx.
Purification MethodsCrystallise the oxime from MeOH (4mL/g). [Beilstein 7 II 355, 7 III 2063 1370.]
Benzophenone oxime Preparation Products And Raw materials
Preparation ProductsBenzophenone imine-->Pyribenzoxim-->(benzhydrylideneamino) benzoate-->Aminodiphenylmethane hydrochloride-->Benzophenone-->Benzenemethanamine, N-hydroxy-a-phenyl-
9-[(ACETYLOXY)IMINO]-2,4,7-TRINITRO-9H-FLUORENE OXIME 10,11-dihydro-5H-dibenzo[a,d]cyclohepten-5-one oxime 5H-dibenzo[a,d]cyclohepten-5-one oxime N4,N4-DIBUTYL-9-HYDROXYIMINO-2,5,7-TRINITRO-9H-FLUORENE-4-CARBOXAMIDE (2-AMINOPHENYL)(PHENYL)METHANONE OXIME (+)-ALPHA-(2,4,5,7-TETRANITRO-9-FLUORENYLIDENEAMINOXY)PROPIONIC ACID 2-AMINO-5-CHLOROBENZOPHENONE OXIME [5-(TERT-BUTYL)-2-HYDROXYPHENYL](PHENYL)METHANONE OXIME 2,4,5,7-TETRANITRO-9H-FLUOREN-9-ONE OXIME 2,4,7-TRINITRO-9H-FLUOREN-9-ONE OXIME (4-[CYANO(DIPHENYL)METHYL]PHENYL)(DIPHENYLMETHYLIDENE)AMMONIUMOLATE (-)-ALPHA-(2,4,5,7-TETRANITRO-9-FLUORENYLIDENEAMINOXY)PROPIONIC ACID N-[BIS(4-FLUOROPHENYL)METHYLENE]-N-[(2,3,3-TRICHLOROALLANOYL)OXY]AMINE 9-OXO-9-OXIME-FLUORENE-4-CARBOXYLIC ACID CHLORDIAZEPOXIDE HYDROCHLORIDE CHLORDIAZEPOXIDE-D5 (+),(-)-A-2,4,5,7-TETRANITRO-9-FLUORENYLIDENEAMINOOXYPROPIONIC ACID

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