ChemicalBook Product Catalog Flavors and fragrances Synthetic fragrances Carboxylic acids and esters Aromatic carboxylic acid ester PIPERONYL ACETATE

PIPERONYL ACETATE

PIPERONYL ACETATE Basic information
Product Name:PIPERONYL ACETATE
Synonyms:(2H-1,3-benzodioxol-5-yl)methyl acetate;Acetic acid 1,3-benzodioxol-5-ylmethyl ester;1,3-Benzodioxol-5-ylmethyl acetate;1,3-benzodioxol-5-ylmethyl ethanoate;Acetic Acid Piperonyl Ester 3,4-Methylenedioxybenzyl Acetate;HELIOTROPYL ACETATE (PIPERONYL ACETATE);PIPERONYL ACETATE 99+%;HELIOTROPYLACETAT
CAS:326-61-4
MF:C10H10O4
MW:194.18
EINECS:206-312-5
Product Categories:Alphabetical Listings;Flavors and Fragrances;O-P
Mol File:326-61-4.mol
PIPERONYL ACETATE Structure
PIPERONYL ACETATE Chemical Properties
Melting point 51°C
Boiling point 150-151 °C10 mm Hg(lit.)
density 1.227 g/mL at 25 °C(lit.)
vapor pressure 0.138-39.5Pa at 20-75℃
refractive index n20/D 1.5265(lit.)
FEMA 2912 | PIPERONYL ACETATE
Fp >230 °F
form Liquid
color A colourless oily liquid with a floral-like odour
Odorat 100.00 %. sweet floral strawberry jam hawthorn metallic
Odor Typefloral
JECFA Number894
Stability:Stable. Combustible.
LogP1.68 at 20℃ and pH7
CAS DataBase Reference326-61-4(CAS DataBase Reference)
NIST Chemistry Reference3,4-Methylenedioxybenzyl acetate(326-61-4)
EPA Substance Registry SystemPiperonyl acetate (326-61-4)
Safety Information
WGK Germany 2
RTECS AI9050000
HS Code 2909.30.6000
toxicityThe acute oral LD50 in rats was reported as 2.1 g/kg (1.81-2.39 g/kg) (Moreno, 1973). The acute dermal LD50 value in rabbits was reported as > 5 g/kg (Moreno, 1973).
MSDS Information
ProviderLanguage
SigmaAldrich English
PIPERONYL ACETATE Usage And Synthesis
Chemical Propertieslight yellow liquid
Chemical PropertiesPiperonyl acetate has a very sweet, light, floral–fruity odor with cherry-like undertones with a sweet, fruity flavor at low levels and bitter at high levels.
OccurrenceReported found in endive (Cichorium endivia L.).
UsesPiperonyl Acetate is a synthetic flavoring agent that is a stable, col- orless to light yellow liquid of heliotrope odor. it should be stored in glass or resin-lined containers. it is used in flavors for berry notes with applications in beverages, candy, ice cream, and baked goods at 50–90 ppm.
PreparationBy acetylation of the corresponding alcohol; by boiling dimethylpiperonyl amine with acetic anhydride.
DefinitionChEBI: Piperonyl acetate is a member of benzodioxoles.
Taste threshold valuesTaste characteristics at 50 ppm: floral, soapy, fruity, berry and slightly jamy with a powdery nuance.
General DescriptionClear pale yellow liquid. Insoluble in water.
Air & Water ReactionsInsoluble in water.
Reactivity ProfilePIPERONYL ACETATE is an ester. Esters react with acids to liberate heat along with alcohols and acids. Strong oxidizing acids may cause a vigorous reaction that is sufficiently exothermic to ignite the reaction products. Heat is also generated by the interaction of esters with caustic solutions. Flammable hydrogen is generated by mixing esters with alkali metals and hydrides.
Health HazardACUTE/CHRONIC HAZARDS: PIPERONYL ACETATE is an irritant.
Fire HazardPIPERONYL ACETATE is combustible.
Safety ProfileModerately toxic by ingestion, A skin irritant. When heated to decomposition it emits acrid smoke and irritating fumes.
bis[(6-nitro-1,3-benzodioxol-5-yl)methyl] pentanedioate PIPERONYL ISOBUTYRATE PIPERONYL PROPIONATE exo-cis-7-Oxabicyclo(2.2.1)heptane-2,3-dicarboxylic acid 3,4-methylene dioxybenzyl ester (6-NITRO-1,3-BENZODIOXOL-5-YL)METHYL 4-METHYLBENZENECARBOXYLATE (6-NITRO-1,3-BENZODIOXOL-5-YL)METHYL 4-NITROBENZENECARBOXYLATE 4-O-butanoyl-4'-demethylpodophyllotoxin PIPERONYL ACETATE 1'-acetoxysafrole steganacin territrem A (6-nitro-1,3-benzodioxol-5-yl)methyl 2-thiophenecarboxylate (6-nitro-1,3-benzodioxol-5-yl)methyl 4-(tert-butyl)benzenecarboxylate Piperonyl alcohol 7-[(2,2,2-TRIFLUOROACETYL)AMINO]-6,7-DIHYDRO-5H-INDENO[5,6-D][1,3]DIOXOL-5-YL 2-THIOPHENECARBOXYLATE (6-nitro-1,3-benzodioxol-5-yl)methyl 3-nitrobenzenecarboxylate (6-NITRO-1,3-BENZODIOXOL-5-YL)METHYL 2-(2,5-CYCLOHEXADIENYLIDEN)ACETATE (6-NITRO-1,3-BENZODIOXOL-5-YL)METHYL 4-FLUOROBENZENECARBOXYLATE
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