ChemicalBook Product Catalog Chemical Reagents Organic reagents Boric acid 4-Bromophenylboronic acid

4-Bromophenylboronic acid

4-Bromophenylboronic acid Basic information
Product Name:4-Bromophenylboronic acid
Synonyms:AKOS BRN-0005;4-BROMOPHENYLBORIC ACID ANHYDRIDE;4-BROMOPHENYLBORONIC ACID;4-BROMOBENZENEBORONIC ACID/ANHYDRIDE;RARECHEM AH PB 0075;P-BROMO BENZENE BORONIC ACID;P-BROMOPHENYLBORONIC ACID;(4-bromophenyl)-boronicaci
CAS:5467-74-3
MF:C6H6BBrO2
MW:200.83
EINECS:226-779-9
Product Categories:Boronate Ester;Potassium Trifluoroborate;OLED materials,pharm chemical,electronic;B (Classes of Boron Compounds);Boronic acids;Boronic Acid;Aryl;Halogenated;Organoborons;Substituted Boronic Acids;blocks;BoronicAcids;Bromides;Boric Acid
Mol File:5467-74-3.mol
4-Bromophenylboronic acid Structure
4-Bromophenylboronic acid Chemical Properties
Melting point 284-288 °C (lit.)
Boiling point 315.0±44.0 °C(Predicted)
density 1.67±0.1 g/cm3(Predicted)
storage temp. Keep in dark place,Sealed in dry,Room Temperature
pka8.32±0.10(Predicted)
form Crystalline Powder
color Off-white to light beige
Water Solubility Soluble in methanol. Insoluble in water.
BRN 2936347
InChIKeyQBLFZIBJXUQVRF-UHFFFAOYSA-N
CAS DataBase Reference5467-74-3(CAS DataBase Reference)
Safety Information
Hazard Codes Xi
Risk Statements 36/37/38-22
Safety Statements 26-36-37/39
WGK Germany 3
RTECS CY8650000
TSCA T
HazardClass IRRITANT
HS Code 29319090
MSDS Information
ProviderLanguage
4-Bromobenzeneboronic acid English
SigmaAldrich English
ACROS English
ALFA English
4-Bromophenylboronic acid Usage And Synthesis
Chemical Propertieswhite to light yellow crystal powde
UsesLabelled 4-Bromophenylboronic Acid (B686545). 4-Bromophenylboric acid is used in the preparation of arylboronates as inhibitors of fatty acid amide hydrolase.
Uses4-Bromobenzeneboronic acid is a reagent used for Palladium catalyzed Suzuki-Miyaura cross-couplings, Tandem-type Pd(II)-catalyzed oxidative Heck reaction and intramolecular C-H amidation sequence. It is also used in the preparation of Protein modulators and enzymatic and kinase inhibitors, Gallate-based obovatol analogs with potential anti-tumor activity. It is used as a reagent for Copper-mediated ligandless aerobic fluoroalkylation of arylboronic acids with fluoroalkyl iodides, Pd-catalyzed arylative cyclization of alkyne-tethered enals or enones via carbopalladation of alkynes, Copper-catalyzed cross-couplings.
Usessuzuki reaction
4-Bromophenylboronic acid Preparation Products And Raw materials
Preparation Products4-Bromobiphenyl-->1533432-50-6-->1-(4-Bromophenyl)-naphthlene-->4-BROMO-4'-METHOXYBENZOPHENONE-->4'-(4,4,5,5-Tetramethyl-1,3,2-dioxaborolan-2-yl)biphenyl-4-carbonitrile-->1-BROMO-4-(2,2-DIFLUOROVINYL)BENZENE-->4-BROMODIPHENYLMETHANE-->5,11-dihydro-5-phenylindolo[3,2-b]carbazole-->METHYL 4'-BROMO[1,1'-BIPHENYL]-4-CARBOXYLATE-->4-Cyclopropyl-benzeneboronic acid-->1-Bromo-4-(phenylsulfonyl)benzene-->4-Bromo diphenylacetylene-->POTASSIUM 4-BROMOPHENYLTRIFLUOROBORATE
2-Fluoro-6-bromophenylboronic acid 2-BROMOPHENYLBORONIC ACID PINACOL ESTER 4-Bromophenylboronic acid N-butyldiethanolamine ester 4-BROMO-2 6-DIFLUOROPHENYLBORONIC ACID 5-BROMO-2-(5,5-DIMETHYL-1,3,2-DIOXABORINAN-2-YL)BENZOIC ACID 4-BROMO-2-AMINO-PHENYLBORONIC ACID Phenylacetone 4-BROMO-3,5-DIFLUOROBENZENEBORONIC ACID 4-BROMO-2,3,5,6-TETRAFLUOROPHENYLBORONIC ACID 4-BROMO-2,5-DIFLUOROBENZENEBORONIC ACID 4-Bromo-2,5-dimethylphenylboronic acid 2-CYANO-5-BROMOPHENYLBORONIC ACID PINACOL ESTER 2-Fluoro-3-ethoxy-6-bromophenylboronic acid (2,4-DIBROMO-5-METHOXY)BENZENEBORONIC ACID 2-(4-BROMO-1-NAPHTHYL)-5,5-DIMETHYL-1,3,2-DIOXABORINANE 3-Bromophenylboronic acid N-butyldiethanolamine ester 4-BROMO-3-NITROPHENYLBORONIC ACID 2-Fluoro-5-bromophenylboronic acid
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