ChemicalBook Product Catalog Inorganic chemistry Inorganic salts Metal halide and Halogen salt Metal chlorides and salt Chromic chloride hexahydrate

Chromic chloride hexahydrate

Chromic chloride hexahydrate Basic information
Product Name:Chromic chloride hexahydrate
Synonyms:hexaaquachromium(iii)chloride;hexaaquachromiumchloride;CHROMIUM(III) CHLORIDE PURE;CHROMIUM(III) CHLORIDE-6-HYDRATE EXTRA PURE, U. S. P.;ChromiumChlorideUsp;Chromium(Iii)ChlorideGr;Chromium(Iii)Nitrate(Nonhydrate)Gr;Chromium(III) chloride hexahydrate, 99.998%
CAS:10060-12-5
MF:Cl3CrH12O6
MW:266.45
EINECS:629-714-6
Product Categories:Catalysis and Inorganic Chemistry;Chemical Synthesis;Chromium;metal halide;chromium salt, electroplating
Mol File:10060-12-5.mol
Chromic chloride hexahydrate Structure
Chromic chloride hexahydrate Chemical Properties
Melting point 83 °C
density 1.76 g/mL at 25 °C(lit.)
storage temp. Inert atmosphere,Room Temperature
solubility Methanol (Slightly), Water (Slightly)
form Powder/Solid
color Reddish-violet
Specific Gravity1.76
PH2.0-3.0
Water Solubility Soluble in water and alcohol. Insoluble in diethyl ether.
Sensitive Hygroscopic
Merck 14,2222
Exposure limitsNIOSH: IDLH 25 mg/m3; TWA 0.5 mg/m3
Stability:Stable, but may be air-sensitive. Hygroscopic. Incompatible with lithium, nitrogen, strong oxidizing agents.
InChIKeyLJAOOBNHPFKCDR-UHFFFAOYSA-K
CAS DataBase Reference10060-12-5(CAS DataBase Reference)
EPA Substance Registry SystemChromium(III) chloride hexahydrate (10060-12-5)
Safety Information
Hazard Codes Xn,N,C
Risk Statements 22-36/37/38-51/53-34
Safety Statements 24/25-61-45-36/37/39-26
RIDADR UN3260
WGK Germany 1
RTECS GB5450000
TSCA Yes
HazardClass 8
PackingGroup III
HS Code 28273985
MSDS Information
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Chromic chloride hexahydrate Usage And Synthesis
Chemical PropertiesChromic chloride hexahydrate is greenish-black to violet deliquescent crystals. soluble in water, ethanol, slightly soluble in acetone, insoluble in ether. It can be used as mordant, chromium additive, chromium reagent for trivalent chromium plating. It can also be used as raw material for the production of other chromium salts and chromium-containing pigments.
UsesChromium(III) chloride hexahydrate is used as an organic synthesis catalyst and as an additive to intravenous solutions.
UsesChromium(III) chloride (CrCl3. 6H2O) hexahydrate can be used:
As a source of chromium(II), which is in turn used as a catalyst in iodovinylation of aldehydes (Takai reaction).
In the synthesis of chromium(III) complexes of tetradentate Schiff bases.
In the preparation of Cr(III)-fatty acid complexes which can further be used as a catalyst for the synthesis of 1-monoacyIgIyceroIs.
In combination with choline chloride as a deep eutectic solvent, which can be utilized as a catalyst for the esterification of formic and acetic acid with alcohols.
Chromic chloride hexahydrate Preparation Products And Raw materials
Raw materialsSodium dichromate dihydrate-->Molasses-->Chromic sulfate-->Chromium(III) chloride-->CHROMIC CARBONATE
Choline chloride Magnesium chloride hexahydrate Nickel chloride Methylene Chloride TRIS(ETHYLENEDIAMINE)CHROMIUM (III) CHLORIDE 8,13-BIS(ETHYL)-3,7,12,17-TETRAMETHYL-21H, 23H-PORPHINE-2,18-DIPROPIONIC ACID CHROMIUM(III) CHLORIDE Chromic chloride hexahydrate Sodium chloride Chromic acid Chromium(VI) oxide chromium(iii) chloride hydrate,CHROMIUM(III) CHLORIDE HYDRATE 99.995% CHROMIUM (III) CHLORIDE TETRAHYDROFURAN COMPLEX Ammonium chloride Chromium(III) chloride Chromyl chloride Chromium CHROMIUM(II) CHLORIDE 2-​[[(2-​ethylphenyl)​(2-​hydroxyethyl)​amino]​methyl]​-​3,​3-​difluoro-Propanenitrile Chromium Trichloride Hexahydrate
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