ChemicalBook Product Catalog Chemical Reagents Organic reagents Thiol ester 2-CHLOROTHIOANISOLE

2-CHLOROTHIOANISOLE

2-CHLOROTHIOANISOLE Basic information
Product Name:2-CHLOROTHIOANISOLE
Synonyms:2-CHLORO THIOANISOLE 99%;(2-chlorophenyl)(methyl)sulfane;1-(Methylthio)-2-chlorobenzene;1-Methylthio-2-chlorobenzene;Methyl (2-chlorophenyl) sulfide;Methyl [2-chlorophenyl] sulfide;Methyl 2-chlorophenyl sulfide;2-Chlorobenzyl thioalcohol
CAS:17733-22-1
MF:C7H7ClS
MW:158.65
EINECS:
Product Categories:Building Blocks;Chemical Synthesis;Organic Building Blocks;Boron, Nitrile, Thio,& TM-Cpds;Sulfides/Disulfides;Sulfur Compounds
Mol File:17733-22-1.mol
2-CHLOROTHIOANISOLE Structure
2-CHLOROTHIOANISOLE Chemical Properties
Boiling point 239-240 °C (lit.)
density 1,22 g/cm3
refractive index n20/D 1.608(lit.)
Fp >230 °F
storage temp. Sealed in dry,Room Temperature
Sensitive Stench
CAS DataBase Reference17733-22-1(CAS DataBase Reference)
Safety Information
Hazard Codes Xi
Risk Statements 36/37/38
Safety Statements 26-36
RIDADR UN 3334
WGK Germany 3
Hazard Note Irritant/Stench
HazardClass STENCH
HS Code 2909309090
MSDS Information
ProviderLanguage
SigmaAldrich English
2-CHLOROTHIOANISOLE Usage And Synthesis
Uses2-Chlorothioanisole may be used to synthesize 2-chlorophenyl methyl sulfone.
Synthesis Reference(s)The Journal of Organic Chemistry, 48, p. 3114, 1983 DOI: 10.1021/jo00166a040
General Description2-Chlorothioanisole can be prepared from the reaction between N,N-dimethylformamide, 1,2-dichlorobenzene, finely ground KOH and methyl mercaptan. Benzene dipole moment value analysis of 2-chlorothioanisole indicates that it exists predominantly in trans- form. 1H NMR spectrum of 2-chlorothioanisole has been studied in acetone-d6 solution.
2-CHLOROTHIOANISOLE Preparation Products And Raw materials
Preparation Products3-Chloro-4-methylsulfanyl-benzaldehyde-->3-chloro-4-Methylthiobenzylchloride-->1-(3-Chloro-4-(methylthio)phenyl)ethanone
TETRASUL 2,4-DICHLOROBENZENESULPHONYLACETONITRILE (2,4-DICHLORO-5-METHYLPHENYLTHIO)ACETIC ACID, 98 2-(2-CHLORO-4-FLUOROPHENYLTHIO)ACETIC ACID Tetradifon [(2,3,4-trichlorophenyl)thio]acetic acid 2,4-DICHLORO-1-[(2-CHLOROETHYL)SULFONYL]BENZENE 2-CHLOROTHIOANISOLE 4-Amino-2-Chlorothioanisole 2,3,5,6-TETRACHLOROTHIOANISOLE 2-(2,3-DICHLOROPHENYLTHIO)ACETIC ACID 2,5-DICHLOROPHENYLTHIOGLYCOLIC ACID 2,4,5-TRICHLOROTHIOANISOLE 2-(2,4-DICHLOROPHENYLTHIO)ACETIC ACID 2,4-BIS(METHYLTHIO)-1-CHLOROBENZENE 6-[(2,5-DICHLOROPHENYL)THIO]PYRIDIN-3-AMINE 2-[(2,4-DICHLOROPHENYL)THIO]ACETONITRILE Butoconazole nitrate
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