Cobalt(II) acetate tetrahydrate

Cobalt(II) acetate tetrahydrate Basic information
Product Name:Cobalt(II) acetate tetrahydrate
Synonyms:COBALT ACETAT;Cobalt(II) acetate tetrahydrate, 99.999% metals basis;Aceticacid,cobalt(2+)salt,tetrahydrate;Cobaltous acetate Bis(acetato)tetraquocobalt;COBALT(II) ACETATE TETRAHYDRATE 98+% &;COBALT(II) ACETATE TETRAHYDRATE, 98+%, A .C.S. REAGENT;COBALT(II) ACETATE TETRAHYDRATE REAGEN&;COBALTOUS ACETATE TETRAHYDRATE, CRYSTALL IZED
CAS:6147-53-1
MF:C4H14CoO8
MW:249.08
EINECS:612-153-6
Product Categories:cobalt , acetate;metal acetate salt;Inorganic Chemicals
Mol File:6147-53-1.mol
Cobalt(II) acetate tetrahydrate Structure
Cobalt(II) acetate tetrahydrate Chemical Properties
Melting point 140 °C
density 1,71 g/cm3
refractive index 1.542
storage temp. Store at +5°C to +30°C.
solubility 348g/l
form Solid
Specific Gravity1.71
color Red
OdorAcetic acid odour
PH7.2 (50g/l, H2O, 20℃)
PH Range6.8
Water Solubility 380 g/L (20 ºC)
Sensitive Hygroscopic
Merck 14,2433
BRN 3731397
Stability:Stable. Avoid moisture, heat.
InChIKeyZBYYWKJVSFHYJL-UHFFFAOYSA-L
CAS DataBase Reference6147-53-1(CAS DataBase Reference)
EPA Substance Registry SystemCobalt acetate tetrahydrate (6147-53-1)
Safety Information
Hazard Codes Xn,N,T
Risk Statements 22-38-40-43-53-50/53-42/43-36/37/38-20/21/22-68-60-49
Safety Statements 36/37-61-45-29-24-22-37/39-36/37/39-26-60-53
RIDADR 3077
WGK Germany 2
RTECS AG3325000
TSCA No
HazardClass 9
PackingGroup III
HS Code 29152300
MSDS Information
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Cobalt(II) acetate tetrahydrate Usage And Synthesis
Chemical PropertiesReddish violet deliequecent crystals.
Uses
  1. Cobalt(II) acetate tetrahydrate is used to prepare complexes for examination of the properties of metals with unusual coordination geometries.
  2. used as a catalyst for oxidation and esterification.
  3. used as an industrial catalyst to harden paints and varnishes, an active catalyst for oxidation and esterification reactions.
UsesCobalt(II) acetate tetrahydrate is used as an industrial catalyst to harden paints and varnishes, an active catalyst for oxidation and esterification reactions. It is also used to prepare metal complexes having unusual coordination geometry.
UsesCobalt(II) acetate tetrahydrate may be used in the preparation of [Co3(OH)2(H2O)2(aptet)4] (aptet = 4-aminophenyltetrazolate) and new tetradentate cobalt(II)-Schiff base complex.
ApplicationCobalt(II) acetate tetrahydrate may be used in the synthesis of the following:
  1. cobalt nanoparticles.
  2. cobalt(II)–aminophenyltetrazolate coordination polymer.
  3. tricobalt complexes with mixed μ-acetato and μ-pyrazolato ligands.
General DescriptionCobalt(II) acetate tetrahydrate has an octahedral structure, the central cobalt orbit is coordinated by four water molecules and two acetate ligands. Cobalt(II) acetate tetrahydrate becomes anhydrous by 140oC.
Safety ProfileModerately toxic by ingestion. Questionable carcinogen. A skin and eye irritant. Human mutation data reported. See also COBUT COMPOUNDS. When heated to decomposition it emits acrid smoke and irritating fumes.
Purification MethodsSeveral recrystallisations from 50% aqueous acetic acid give the tetrahydrate. It is converted to the anhydrous salt by drying at 80o/1mm for 60hours. [Beilstein 2 IV 120.]
Cobalt(II) acetate tetrahydrate Preparation Products And Raw materials
Raw materialsCobalt acetate
Preparation ProductsCOBALT TPP-->(R,R)-(-)-N,N'-BIS(3,5-DI-TERT-BUTYLSALICYLIDENE)-1,2-CYCLOHEXANEDIAMINO-COBALT(II)-->5,10,15,20-Tetrakis-(4-aminophenyl)-porphyrin-Co-(II)
Sodium acetate Ammonium acetate COBALT(II) PHOSPHATE OCTAHYDRATE Hydrazinium hydroxide solution Cobalt acetate Chloroacetic acid Trifluoroacetic acid Cellulose acetate Tricobalt tetraoxide Cobalt naphthenate ACETATE Ethyl acetate Glatiramer acetate COBALT ALUMINUM OXIDE Vinyl acetate Acetic acid Cobalt decanoate Cobalt

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