ChemicalBook Product Catalog Chemical Reagents Organic reagents Aliphatic aldehydes 2-NITROCINNAMALDEHYDE

2-NITROCINNAMALDEHYDE

2-NITROCINNAMALDEHYDE Basic information
Product Name:2-NITROCINNAMALDEHYDE
Synonyms:O-NITROCINNAMALDEHYDE;AKOS BBS-00003259;3-(2-NITROPHENYL)ACRYLALDEHYDE;2'-NITROCINNAMALDEHYDE;2-NITROCINNAMALDEHYDE;2-NITROPHENYLACROLEIN;2-NITROPHENYLACRYLALDEHYDE;2''-NITROCINNAMALDEHYDE 98+%
CAS:1466-88-2
MF:C9H7NO3
MW:177.16
EINECS:215-988-0
Product Categories:Aromatic Aldehydes & Derivatives (substituted)
Mol File:1466-88-2.mol
2-NITROCINNAMALDEHYDE Structure
2-NITROCINNAMALDEHYDE Chemical Properties
Melting point 127-129 °C(lit.)
Boiling point 309.06°C (rough estimate)
density 1.3312 (rough estimate)
refractive index 1.5200 (estimate)
storage temp. Store below +30°C.
form Crystals or Powder
color Light yellow to yellow-brown
Water Solubility Soluble in methanol. Insoluble in water.
Sensitive Air Sensitive
BRN 908376
CAS DataBase Reference1466-88-2(CAS DataBase Reference)
Safety Information
Hazard Codes Xi
Risk Statements 36/38-43
Safety Statements 26-36-36/37
WGK Germany 3
HS Code 29130000
MSDS Information
ProviderLanguage
SigmaAldrich English
ACROS English
ALFA English
2-NITROCINNAMALDEHYDE Usage And Synthesis
Chemical Propertieslight yellow to yellow-brown crystals or powder
UsesIt finds its uses as a actinometer for the UV-A range of photostability testing of pharmaceuticals. 2-Nitrocinnamaldehyde can be oxidized to 2-nitrocinnamic acid which can be used in the Baeyer-Emmerling indole synthesis to produce indole and substituted indoles.
Synthesis Reference(s)Tetrahedron Letters, 31, p. 4497, 1990 DOI: 10.1016/S0040-4039(00)97659-7
2-NITROCINNAMALDEHYDE Preparation Products And Raw materials
3-(4,5-DIMETHOXY-2-NITROPHENYL)-N-(4-FLUOROPHENYL)ACRYLAMIDE 3-(4,5-DIMETHOXY-2-NITROPHENYL)-N-((4-CHLOROPHENYL)METHYL)PROP-2-ENAMIDE 4,5-METHYLENEDIOXY-2-NITROCINNAMIC ACID 2-(2,2-DIMETHYLPROPANOYL)-3-(2-NITROPHENYL)PROP-2-ENENITRILE (E)-3-(4,5-dimethoxy-2-nitrophenyl)-1-piperidino-2-propen-1-one 2-NITROCINNAMALDEHYDE (E)-N-[4-(tert-butyl)phenyl]-3-(4,5-dimethoxy-2-nitrophenyl)-2-propenamide 3-(4,5-DIMETHOXY-2-NITROPHENYL)-1-MORPHOLINO-2-PROPEN-1-ONE 3-(4,5-DIMETHOXY-2-NITROPHENYL)-2-(2,2-DIMETHYLPROPANOYL)PROP-2-ENENITRILE 4,5-DIMETHOXY-2-NITROCINNAMIC ACID 2-NITROCHALCONE 2-NITROCINNAMIC ACID 2,2-DIMETHYL-5-((2-NITROPHENYL)METHYLENE)-1,3-DIOXANE-4,6-DIONE 3-[4-(BENZYLOXY)-5-METHOXY-2-NITROPHENYL]ACRYLIC ACID (E)-N-(3-chlorophenyl)-3-(4,5-dimethoxy-2-nitrophenyl)-2-propenamide 2-Nitrobenzeneacrylic acid methyl ester (6-NITROBENZO[1,3]-DIOXOL-5-YL)-1-PHENYL-PROPENE-1-ONE (E)-3-(4,5-dimethoxy-2-nitrophenyl)-1-(4-methylpiperazino)-2-propen-1-one
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