B-ISOPINOCAMPHEYL-9-BORABICYCLO[3.3.1]NONANE

B-ISOPINOCAMPHEYL-9-BORABICYCLO[3.3.1]NONANE Basic information
Product Name:B-ISOPINOCAMPHEYL-9-BORABICYCLO[3.3.1]NONANE
Synonyms:S-alpine-borane (0.5M soln. in thf);S-Alpine-Borane? S-2,6,6-trimethyl-4-(9-borabicyclo(3.3.1)nonane-9-yl)-bicyclo(3.1.1)heptane;S-B-isopinocampheyl-9-borabicyclo(3.3.1)nonane;S-ALPINE-BORANE 97% NEAT LIQUID;(S)-(+)-1,2-Isopropylideneglycerol, 98% (99% ee/GLC);s-alpine-borane tm solution;isopinocampheylborane derivative;S-Alpine-Borane(R) solution
CAS:42371-63-1
MF:C18H31B
MW:258.25
EINECS:
Product Categories:API intermediates
Mol File:42371-63-1.mol
B-ISOPINOCAMPHEYL-9-BORABICYCLO[3.3.1]NONANE Structure
B-ISOPINOCAMPHEYL-9-BORABICYCLO[3.3.1]NONANE Chemical Properties
Boiling point >55 °C(lit.)
density 0.897 g/mL at 25 °C
Fp 1 °F
optical activity[α]22/D +20°, c = 12 in THF
Safety Information
Hazard Codes F,Xn,Xi
Risk Statements 11-19-22-36/37/38-17-40-36/37
Safety Statements 16-26-27-36/37/39-24-6-36-36/37
RIDADR UN 1993 3/PG 2
WGK Germany 3
HazardClass 4.3
PackingGroup III
MSDS Information
ProviderLanguage
SigmaAldrich English
B-ISOPINOCAMPHEYL-9-BORABICYCLO[3.3.1]NONANE Usage And Synthesis
UsesR- and S-Alpine-Boranes are used for asymmetric reduction of aldehydes and prochiral ketones.
General DescriptionS-Alpine-Borane? is a chiral reducing agent, synthesized from (-)-α-pinene via hydroboration.
B-ISOPINOCAMPHEYL-9-BORABICYCLO[3.3.1]NONANE Preparation Products And Raw materials
Triethylborane B-ISOPINOCAMPHEYL-9-BORABICYCLO[3.3.1]NONANE,(R)-B-isopinocampheyl-9-borabicyclo[3.3.1]nonane,b-isopinocampheyl-9-borabicyclo[3.3.1]nonane solution TRIBUTYLBORANE B-ISOPINOCAMPHEYL-9-BORABICYCLO[3.3.1]NONANE 9-Borabicyclo[3.3.1]nonane TRI-SEC-BUTYLBORANE 9-BBN-NOPOL BENZYL ETHER ADDUCT (1S)-(-)-CIS-PINAME PINANE LITHIUM B-ISOPINOCAMPHEYL-9-BORABICYCLO[3.3.1]NONYL HYDRIDE

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