Chemical Properties | Colorless liquid; oily aroma. |
Uses | Methyl 10-undecenoate, unsaturated fatty acid ester, is used to modify commercial silicone monomer, 1,3,5,7-tetramethylcyclotetrasiloxane for the preparation of silicone hollow nano/microstructures in water. |
Uses | Methyl 10-undecenoate is an unsaturated fatty acid ester that can be used as a substrate:
- To prepare bifunctional polymer precursors via hydroformylation reaction.
- To synthesize α,ω-ester amides via aminocarbonylation in the presence of palladium catalyst.
- To modify commercial silicone monomer, 1,3,5,7-tetramethylcyclotetrasiloxane, for the preparation of silicone hollow nano/microstructures in water by hydrosilylation reaction.
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Definition | ChEBI: A fatty acid methyl ester of 10-undecenoic acid. |
Aroma threshold values | Medium strength odor, fatty type |
Synthesis Reference(s) | The Journal of Organic Chemistry, 54, p. 3015, 1989 DOI: 10.1021/jo00274a010 Tetrahedron, 52, p. 915, 1996 DOI: 10.1016/0040-4020(95)00950-7 Synthetic Communications, 3, p. 281, 1973 DOI: 10.1080/00397917308065917 |
General Description | Methyl 10-undecenoate is the chain stopper in the polymerization of long-chain aliphatic α,ω-diene through acyclic diene metathesis (ADMET). This helps in tuning the molecular weight of the resulting polyester in a range varying from 10 to 45 kDa. |
Flammability and Explosibility | Nonflammable |