2-Chloro-1,3-dimethylimidazolidinium tetrafluoroborate

2-Chloro-1,3-dimethylimidazolidinium tetrafluoroborate Basic information
Product Name:2-Chloro-1,3-dimethylimidazolidinium tetrafluoroborate
Synonyms:2-CHLORO-1,3-DIMETHYLIMIDAZOLIDINIUM TETRAFLUOROBORATE;2-CHLORO-1,3-DIMETHYL-2-IMIDAZOLINIUM TETRAFLUOROBORATE;2-CHLORO-1,3-DIMETHYLIMIDAZOLIDINIUM BF4;CIB;CIB REAGENT;2-CHLORO-1 3-DIMETHYL-2-IMIDAZOLINIUM &;2-Chloro-1,3-dimethylimidazolidiniumtetrafluorobo;CIB2-Chloro-1,3-dimethylimidazolidiniumtetrafluoroborate
CAS:153433-26-2
MF:C5H10ClN2.BF4
MW:220.4
EINECS:623-751-1
Product Categories:Coupling Reagent
Mol File:153433-26-2.mol
2-Chloro-1,3-dimethylimidazolidinium tetrafluoroborate Structure
2-Chloro-1,3-dimethylimidazolidinium tetrafluoroborate Chemical Properties
Melting point 175-177 °C(lit.)
storage temp. 2-8°C
solubility acetonitrile: 0.1 g/mL, clear
form Powder or Crystalline Powder
color White to off-white
Sensitive Moisture & Light Sensitive
InChIKeyUPLXKEIRISBKRM-UHFFFAOYSA-N
CAS DataBase Reference153433-26-2(CAS DataBase Reference)
Safety Information
Hazard Codes Xi
Risk Statements 36/37/38
Safety Statements 26-36
WGK Germany 3
8-10-21
HS Code 29332900
MSDS Information
ProviderLanguage
SigmaAldrich English
2-Chloro-1,3-dimethylimidazolidinium tetrafluoroborate Usage And Synthesis
Chemical PropertiesColorless to white crystalline powder
Uses2-Chloro-1,3-dimethylimidazolium tetrafluoroborate is a reagent for esterification of C-terminal amino acids to Wang resin without racemization and for coupling α,α-dimethyl amino acids; and for preparation of the benzotriazol-1-yloxy derivative, a new coupling reagent. It is used as a reagent for esterification and peptide coupling of sterically hindered amino acids; preparation of efficient diazo-transfer reagents; oxidative insertion for palladium and nickel catalyst synthesis; and preparation of catalysts for use in coupling reactions.
UsesReagent for:
Esterification and peptide coupling of sterically hindered amino acids
Preparation of efficient diazo-transfer reagents
Oxidative insertion for palladium and nickel catalyst synthesis
Preparation of catalysts for use in coupling reactions
2-Chloro-1,3-dimethylimidazolidinium tetrafluoroborate Preparation Products And Raw materials
2-Chloro-1,3-dimethylimidazolidinium hexafluorophosphate 2-Fluoro-1,3-dimethylimidazolidinium hexafluorophosphate 2-Chloro-1,3-dimethylimidazolidinium chloride 2-Chloro-1,3-dimethylimidazolidinium tetrafluoroborate tert-Butyldimethylsilyl chloride Dimefluthrin Difluorochloromethane AZURE B TETRAFLUOROBORATE TRIETHANOLAMINE BORATE Fluoroboric acid

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