[1,1'-Bis(diphenylphosphino)ferrocene]dichloropalladium(II)

[1,1'-Bis(diphenylphosphino)ferrocene]dichloropalladium(II) Basic information

Product Name:	[1,1'-Bis(diphenylphosphino)ferrocene]dichloropalladium(II)
Synonyms:	1,1'-BIS(DIPHENYLPHOSPHINO)FERROCENEDICHLOROPALLADIUM(II);1,1-BIS(DIPHENYLPHOSPHINO)FERROCENEDICHLOROPALLADIUM(II);1,1'-BIS(DIPHENYLPHOSPHINO)FERROCENE PALLADIUM DICHLORIDE;1,1'-BIS(DIPHENYLPHOSPHINO)FERROCENEPALLADIUM(II) DICHLORIDE;PDCL2(DPPF);Dichloro(1,1'-bis(diphenylphosphino)ferrocene)palladium (II) dichloromethane add;1,1'-Bis(diphenylphosphino)ferroceneüpalladium(II) chloride, 1:1 complex with dichloromethane;[bis(diphenylphosphino)ferrocene]PdCl2/ dichloromethane
CAS:	72287-26-4
MF:	C34H28Cl2FeP2Pd
MW:	731.7
EINECS:	460-040-3
Product Categories:	Pd;Catalysts-Ligands;Metal Compounds;pharmacetical;API intermediates;Catalysts for Organic Synthesis;Classes of Metal Compounds;Fe (Iron) Compounds;Ferrocenes;Homogeneous Catalysts;Metal Complexes;Catalysis and Inorganic Chemistry;Homogeneous Pd Catalysts;Palladium;Metallocenes;Pd (Palladium) Compounds;Synthetic Organic Chemistry;Transition Metal Compounds;72287-26-4
Mol File:	72287-26-4.mol

[1,1'-Bis(diphenylphosphino)ferrocene]dichloropalladium(II) Chemical Properties

Melting point	275-280 °C(lit.)
storage temp.	Keep in dark place,Inert atmosphere,Room temperature
solubility	Soluble in dichloromethane.
form	powder
color	red to very dark red
Stability:	Hygroscopic

Safety Information

MSDS Information

[1,1'-Bis(diphenylphosphino)ferrocene]dichloropalladium(II) Usage And Synthesis

Uses	[1,1′-Bis(diphenylphosphino)ferrocene]dichloropalladium(II), is a palladium catalyst used in chemical synthesis of various compounds.Is used in preparation of Nucleosides as Ectonucleotidase inhibitors.
Chemical Properties	[1,1'-Bis(diphenylphosphino)ferrocene]dichloropalladium(II) is Red solid
Uses	[1,1'-Bis(diphenylphosphino)ferrocene]dichloropalladium(II) is used as a catalyst for Suzuki and Stile couplings.
Uses	Catalyst for C-C and C-N coupling reaction.
Uses	suzuki reaction
Application	[1,1'-Bis(diphenylphosphino)ferrocene]dichloropalladium(II) may be used as an effective palladium catalyst in the following reactions: Cross-coupling of sec-alkyl and n-alkyl Grignard reagents with high yield and selectivity. Suzuki coupling of aryl boronic esters with [11C]methyl iodide to form functionalized [11C]toluene derivatives. Kumada cross-coupling of 1,3,5-tribromobenzene with Grignard reagents to form star-shaped oligothiophenes.
Mechanism of action	[1,1'-Bis(diphenylphosphino)ferrocene]dichloropalladium(II) (pd(dppf)cl2) catalysis has gained widespread use in industrial and academic synthetic chemistry laboratories as a powerful methodology for the formation of C-C and C-Heteroatom bonds. R = usually sp2 hybridised carbon X = usually I, Br, Cl or OTf The nature of R' and M are dependant upon the specic coupling being performed

[1,1'-Bis(diphenylphosphino)ferrocene]dichloropalladium(II) Preparation Products And Raw materials

Raw materials	Ethanol-->Methanol-->Dichloromethane-->Toluene-->Acetonitrile-->Palladium chloride-->Lithium chloride-->1,1'-Bis(diphenylphosphino)ferrocene
Preparation Products	3-MORPHOLINOPHENYLBORONIC ACID PINACOL ESTER-->Vanadyl acetylacetonate-->4-Nitrophenylboronic acid-->4-AMINO-3-METHOXYPHENYLBORONIC ACID, PINACOL ESTER-->2-Ethoxycarbonylphenylboronic acid pinacol ester

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