ARSENIC PENTASULPHIDE

ARSENIC PENTASULPHIDE Basic information
Product Name:ARSENIC PENTASULPHIDE
Synonyms:ARSENIC(V) SULFIDE;ARSENIC PENTASULPHIDE;ARSENIC(V) SULFIDE, 99.99+%;As2S3;Diarsenic pentasulfide;Arsenic sulfide (as2S5);Arsenicpentasulfide;diarsenicpentasulphide
CAS:1303-34-0
MF:As2S5
MW:310.17
EINECS:
Product Categories:ArsenicMaterials Science;Catalysis and Inorganic Chemistry;Chalcogenides;Chemical Synthesis;Metal and Ceramic Science
Mol File:1303-34-0.mol
ARSENIC PENTASULPHIDE Structure
ARSENIC PENTASULPHIDE Chemical Properties
Melting point >300 °C (lit.)
form brown-yellow amorphous solid
Water Solubility g/L solution H2O: 0.00136 (0°C) [KRU93]
Merck 13,807
CAS DataBase Reference1303-34-0
EPA Substance Registry SystemArsenic pentasulfide (1303-34-0)
Safety Information
Hazard Codes T,N
Risk Statements 23/25-50/53
Safety Statements 20/21-28-45-60-61
RIDADR UN 1557 6.1/PG 2
WGK Germany 3
HazardClass 6.1(b)
PackingGroup III
MSDS Information
ProviderLanguage
SigmaAldrich English
ARSENIC PENTASULPHIDE Usage And Synthesis
Chemical PropertiesARSENIC PENTASULPHIDE is yellow or orange powder(s); stable in air up to 95°C; can be prepared by fusing As and S or by passing H2S through HCl solution of arsenic acid; used as a paint pigment, in light filters [HAW93] [KIR78]
Physical propertiesYellow-brown glassy amorphous solid; sublimes on heating; decomposes around 500°C; insoluble in cold water (~1.4 mg/L at 0°C); dissolves in alkalies and solutions of alkali metal sulfides, and in nitric acid.
UsesARSENIC PENTASULPHIDE is used for preparation of glasses with small gold additions posessing photoluminescent and conductive properties 1 Reactant for preparation of silver thioarsenate complex ethylenediammonium salt 2
UsesIn thin sheets as a light filter; in pigments.
Uses
  • Used for preparation of glasses with small gold additions posessing photoluminescent and conductive properties
  • Reactant for preparation of silver thioarsenate complex ethylenediammonium salt
PreparationArsenic pentasulfide is prepared by precipitation from an acidic solution of orthoarsenic acid, H3AsO4, or arsenic pentachloride, AsCl5 or any other soluble As(V) salt by passing hydrogen sulfide. It may be also prepared by heating a mixture of arsenic and sulfur, extracting the fused mass with ammonia solution and reprecipitating arsenic pentasulfide at low temperature by addition of HCl.
ARSENIC PENTASULPHIDE Preparation Products And Raw materials
Diantimony trioxide SILVER(I) SULFIDE BISMUTH SULFIDE RUBIDIUM ARSENIC PENTASULPHIDE Arsenic(II) sulfide, tech. 90%,ARSENIC (II) SULFIDE ARSENIC (III) SULFIDE ARSENIC (II) SULFIDE

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