Diantimony pentoxide

Diantimony pentoxide Basic information
Product Name:Diantimony pentoxide
Synonyms:ANTIMONY PENTOXIDE;Antimonic“acid”;ANTIMONY(V) OXIDE 85%;ANTIMONY(V) OXIDE, 99.995%;Antimony(V) oxide, 99+%;Antimony(V) oxide;Antimony pentoxide;ANTIMONY(V)OXIDE, 99.999%;Antimony(V)oxide(99.9%-Sb)
CAS:1314-60-9
MF:O5Sb2
MW:323.52
EINECS:215-237-7
Product Categories:metal oxide;Inorganics;Industrial/Fine Chemicals
Mol File:1314-60-9.mol
Diantimony pentoxide Structure
Diantimony pentoxide Chemical Properties
Melting point 380 °C (dec.)(lit.)
density 3.78 g/mL at 25 °C(lit.)
form Powder
Specific Gravity3.8
color Yellow
Water Solubility Slightly soluble in water. Slowly dissolves in warm HCl and warm KOH. Insoluble in HNO<sub>3</sub>
Merck 14,698
Exposure limitsACGIH: TWA 0.5 mg/m3
NIOSH: IDLH 50 mg/m3; TWA 0.5 mg/m3
Stability:Stable. Incompatible with acids, reducing agents.
CAS DataBase Reference1314-60-9(CAS DataBase Reference)
EPA Substance Registry SystemAntimony oxide (Sb2O5) (1314-60-9)
Safety Information
Hazard Codes Xi
Risk Statements 36/37/38
Safety Statements 26-36
RIDADR 1549
WGK Germany 3
RTECS CC6300000
TSCA Yes
HazardClass 6.1
PackingGroup III
ToxicityLD50 i.p. in rats: 400.0 mg Sb/100 g (Bradley, Fredrick)
MSDS Information
ProviderLanguage
SigmaAldrich English
ACROS English
ALFA English
Diantimony pentoxide Usage And Synthesis
Chemical Propertiesyellow powder
Physical propertiesYellow powdery solid; density 3.80 g/ cm3; very slightly soluble in water; hydrated pentoxide is insoluble in nitric acid; dissolves in an aqueous solution of caustic potash.
UsesIt is used as flame retardants in acrylonitrile-butadiene-styrene (ABS) polymer, plastics, rubbers, paper and textiles. It finds use as a flocculant in the production of titanium dioxide. It also finds use in ion-exchange resin. It is also employed as catalyst in certain polymerization and oxidation reactions.
UsesFire retardant in clothing.
UsesAntimony pentoxide (Sb2O3) is used as a flame retardant for textile materials and as a source to prepare other antimony compounds.
DefinitionA yellow solid. It is usually formed by the action of concentrated nitric acid on antimony or by the hydrolysis of antimony(V) chloride. Although an acidic oxide, it is only slightly soluble in water.
PreparationThe hydrated oxide is prepared by hydrolysis of antimony pentachloride; or by acidification of potassium hexahydroxoantimonate(V), KSb(OH)6 [12208- 13-8]. The product, filtered and air dried at ambient temperature has approximate composition Sb2O5 ? 3.5H2O. It may be also prepared by oxidation of antimony trioxide with nitric acid.
Flammability and ExplosibilityNonflammable
Safety ProfileModerately toxic by intraperitoneal route. See also ANTIMONY COMPOUNDS.
Diantimony pentoxide Preparation Products And Raw materials
Raw materialsHydrogen peroxide-->Diantimony trioxide
Preparation Productsantimony pentoxide sol-->1,2-DICHLOROTETRAFLUOROETHANE
ANTIMONY (IV) OXIDE Antimony Tellurium dioxide Acetic anhydride Calcium oxide Maleic anhydride Diantimony pentoxide Zinc oxide Hydrogen peroxide Succinic anhydride Trimellitic Anhydride Chromium(VI) oxide ARSENIC PENTOXIDE Vanadium(V) oxide Phthalic anhydride Glutaric anhydride Cobalt chromite green spinel Calcium hydroxide

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