Ethyl propionate

Ethyl propionate Basic information
Product Name:Ethyl propionate
Synonyms:ETHYL PROPIONATE;FEMA 2456;RARECHEM AL BI 0159;PROPIONIC ACID ETHYL ESTER;C2H5COOC2H5;Ethyl ester of propanoic acid;Ethyl n-propionate;Ethylester kyseliny propionove
CAS:105-37-3
MF:C5H10O2
MW:102.13
EINECS:203-291-4
Product Categories:Alphabetical Listings;Certified Natural ProductsFlavors and Fragrances;E-F;Flavors and Fragrances;Alpha Sort;Chemical Class;E;E-LAlphabetic;EQ - EZAnalytical Standards;Esters;EstersSaturated fatty acids and derivatives;Ethyl Ester;Volatiles/ Semivolatiles;Organics;Morpholines/Thiomorpholines;C2 to C5Saturated fatty acids and derivatives;Carbonyl Compounds;K00001
Mol File:105-37-3.mol
Ethyl propionate Structure
Ethyl propionate Chemical Properties
Melting point -73 °C (lit.)
Boiling point 99 °C (lit.)
density 0.888 g/mL at 25 °C (lit.)
vapor density 3.52 (vs air)
vapor pressure 40 mm Hg ( 27.2 °C)
FEMA 2456 | ETHYL PROPIONATE
refractive index n20/D 1.384(lit.)
Fp 54 °F
storage temp. Flammables area
solubility 17g/l
form Liquid
color Clear colorless to pale yellow
PH7 (H2O, 20℃)
Odorat 10.00 % in dipropylene glycol. sweet fruity rum juicy fruit grape pineapple
Odor Typefruity
Odor Threshold0.007ppm
explosive limit1.8-11%(V)
Water Solubility 25 g/L (15 ºC)
Merck 14,3847
JECFA Number28
BRN 506287
InChIKeyFKRCODPIKNYEAC-UHFFFAOYSA-N
LogP1.31 at 22.1℃
CAS DataBase Reference105-37-3(CAS DataBase Reference)
NIST Chemistry ReferencePropanoic acid, ethyl ester(105-37-3)
EPA Substance Registry SystemEthyl propionate (105-37-3)
Safety Information
Hazard Codes F
Risk Statements 11
Safety Statements 16-23-24-29-33
RIDADR UN 1195 3/PG 2
WGK Germany 1
RTECS UF3675000
Autoignition Temperature887 °F
TSCA Yes
HazardClass 3
PackingGroup II
HS Code 29159000
Hazardous Substances Data105-37-3(Hazardous Substances Data)
MSDS Information
ProviderLanguage
ACROS English
SigmaAldrich English
ALFA English
Ethyl propionate Usage And Synthesis
Chemical Propertiesclear colorless to pale yellow liquid
Chemical PropertiesEthyl propionate has an odor reminiscent of rum and pineapple.
Chemical PropertiesEthyl Propionate is found in many fruits and alcoholic beverages. It has a fruity odor reminiscent of rum and is used in flavor compositions for creating both fruity and rum notes.
OccurrenceReported found in several types of wine, in white grape var. Sauvignon, cocoa, apple juice, orange juice, grapefruit juice, guava, melon, peach, pineapple, strawberry, tomato, various cheeses, beer, cognac, rum, whiskey, bourbon, malt whiskey, scotch, cider, brandy, kiwi fruit and mussels.
UsesSolvent for cellulose ethers and esters, various natural and synthetic resins; flavoring agent; fruit syrups; cutting agent for pyroxylin.
UsesEthyl Propionate is a flavoring agent that is a transparent liquid, colorless, with an odor resembling rum. it is miscible in alcohol and propylene glycol, soluble in fixed oils, mineral oil, and alcohol, and sparingly soluble in water. it is obtained by chemical synthesis.
DefinitionChEBI: A propanoate ester of ethanol.
Production MethodsEthyl propionate is produced by the esterification of ethyl alcohol with propionic acid or propionic anhydride.
PreparationFrom propionic acid, ethyl alcohol and concentrated H2SO4 in chloroform at the boil
Aroma threshold valuesDetection: 9 to 45 ppb
Taste threshold valuesTaste characteristics at 25 ppm: sharp, fermented, rummy and fruity.
General DescriptionA clear colorless liquid with a pineapple-like odor. Flash point 54°F. Less dense than water and insoluble in water. Vapors are heavier than air.
Air & Water ReactionsHighly flammable. Insoluble in water.
Reactivity ProfileEthyl propionate is an ester. Esters react with acids to liberate heat along with alcohols and acids. Strong oxidizing acids may cause a vigorous reaction that is sufficiently exothermic to ignite the reaction products. Heat is also generated by the interaction of esters with caustic solutions. Flammable hydrogen is generated by mixing esters with alkali metals and hydrides. Can react with oxidizing agents, bases, and acids. Polymerization: Will not polymerize [USCG, 1999].
HazardFlammable, dangerous fire risk.
Health HazardExposure can cause irritation of eyes, nose and throat. May cause shortness of breath or coughing. High concentrations have a narcotic effect. May cause abdominal pain and vomiting if swallowed.
Safety ProfileModerately toxic by ingestion and intraperitoneal routes. A skin and eye irritant. A flammable liquid. A very dangerous fire and explosion hazard when exposed to heat or flame; can react vigorously with oxidizing materials. To fight fire, use foam, CO2, dry chemical. When heated to decomposition it emits acrid smoke and irritating fumes. See also ETHERS.
Purification MethodsTreat the ester with anhydrous CuSO4 and distil it under nitrogen. [Beilstein 2 IV 205.]
Ethyl 2-bromovalerate 2-[[4-[[2-acetamido-4-(diethylamino)phenyl]azo]-5-methoxy-2-methylphenyl]sulphonyl]ethyl propionate 2-ISONITRILO-2-METHYL ETHYL PROPANOATE (2-METHYL-1H-INDOL-3-YL)-OXO-ACETIC ACID ETHYL ESTER 2-(2-chloroethylsulfanyl)ethyl propanoate 3-ISONITRILO ETHYL PROPANOATE 2-(4-{4-[4-cyclopentyl(propionyl)anilino]butyl}-1-piperazinyl)ethyl propionate 2-[N-(2-cyanoethyl)anilino]ethyl propionate (1-phenyl-2-propanoyloxy-ethyl) propanoate 2-ISONITRILO-ETHYL PROPANOATE 2-(2-Methyl-1,2,3,3a,4,5,6,6a-octahydaocyclopenta(b)pyrrol-1-yl)ethyl propionate propanoate 3-Ethoxy Ethyl Propionate Ethyl 2-bromoheptanoate 2-(dimethylamino)ethyl propionate 1-Methyl-1-(4-methyl-3-cyclohexen-1-yl)ethyl propionate 2-(5-methylthiazol-4-yl)ethyl propionate 2-[N-(2-cyanoethyl)-4-[(4-nitrophenyl)azo]anilino]ethyl propionate

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