Murexide

Murexide Basic information
Product Name:Murexide
Synonyms:Acid ammonium purpurate,Ammonium purpurate,5,5'-Nitrilodibarbituric acid ammonium salt;5,5'-NITRILODIBARBITURIC ACID MONOAMMONIUM SALT;ammonium 5-(2,4,6-trioxoperhydropyrimidin-5-ylideneamino)barbiturate;AMMONIUM PERPURATE;AMMONIUM PURPURATE;AMMONIUM PURPURATE ACID;Purpuric Acid, Ammonium Salt;MUREXIDE A.C.S. REAGENT
CAS:3051-09-0
MF:C8H8N6O6
MW:284.19
EINECS:221-266-6
Product Categories:Chemical Synthesis;Colours, Dyes, Indicators & Pigments
Mol File:3051-09-0.mol
Murexide Structure
Murexide Chemical Properties
Melting point 300 °C
Boiling point 443.25°C (rough estimate)
density 1.5756 (rough estimate)
refractive index 1.8000 (estimate)
storage temp. no restrictions.
solubility 1g/l
form Solid
Colour Index 56085
pkapK1:0.0;pK2:9.20;pK3:10.50 (25°C)
color Reddish-violet
OdorOdorless
PH5 (1g/l, H2O, 20℃)
Water Solubility Slightly soluble
Merck 14,6306
BRN 3582175
InChIKeyHZRQHQKDQSVFMQ-UHFFFAOYSA-N
NIST Chemistry ReferenceAmmonium purpurate(3051-09-0)
EPA Substance Registry System2,4,6(1H,3H,5H)-Pyrimidinetrione, 5-[(hexahydro-2,4,6-trioxo-5-pyrimidinyl)imino]-, monoammonium salt (3051-09-0)
Safety Information
Hazard Codes Xn
Risk Statements 22-40
Safety Statements 24/25-22-36/37
WGK Germany 3
TSCA Yes
HS Code 29335995
MSDS Information
ProviderLanguage
Ammonium purpurate English
ACROS English
ALFA English
Murexide Usage And Synthesis
Chemical PropertiesBordeaux powder
UsesIndicator for complexometric titrations.
UsesMurexide is used as a complexometric indicator in analytical chemistry for complexometric titrations of calcium, copper nickel and cobalt. It is an inhibitor of dihydrofolate reductase. Further, it acts as an enhancer of sonochemical destruction of chlorinated hydrocarbon pollutants.
Purification MethodsThe sample may be grossly contaminated with uramil, alloxanthine, etc., and may be difficult to purify. It is better to synthesise it from pure alloxanthine [Davidson J Am Chem Soc 58 1821 1936]. Recrystallise it from water. [Kuhn & Lyman Chem Ber 69 1547 1936, Beilstein 25 I 709, 25 III/IV 4236.]
Murexide Preparation Products And Raw materials
Raw materialsChromium(VI) oxide-->Ammonium acetate-->URAMIL-->ALLOXANTIN-->Dimethylamine-->Water
Barbituric acid TETRAMETHYLMUREXIDE AMMONIUM SALT MUREXIDE, MONOHYDRATE,CI 56085 5,6-DIHYDROURACIL Malonamide Ammonium formate Murexide Ammonium nitrate Hexahydro-pyrimidine TRI-AMMONIUM ORTHOPHOSPHATE Propyleneurea Ammonium citrate tribasic Ammonium acetate Molybdic acid Ammonium metavanadate Barbiturate 5-Aminouracil Ammonium ferric citrate

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