Diacetoxydimethylsilane

Diacetoxydimethylsilane Basic information
Features
Product Name:Diacetoxydimethylsilane
Synonyms:(Acetyloxy)(dimethyl)silyl acetate;Dimethyldiacetoxysilicane;dimethyl-silanediodiacetate;Dimethylsilanediol, diacetate;Silanediol,dimethyl-,diacetate;LABOTEST-BB LT01406985;DIACETOXYDIMETHYLSILANE;DIMETHYLDIACETOXYSILANE
CAS:2182-66-3
MF:C6H12O4Si
MW:176.24
EINECS:218-562-2
Product Categories:Crosslinkers;Crosslinking Agents;Functional Materials;Si (Classes of Silicon Compounds);Silane Coupling Agents;Silane Coupling Agents (Intermediates);Silyl Esters;Si-O Compounds;Acetoxy Silanes
Mol File:2182-66-3.mol
Diacetoxydimethylsilane Structure
Diacetoxydimethylsilane Chemical Properties
Melting point -12.5 °C (lit.)
Boiling point 163 °C (lit.)
density 1.054 g/mL at 25 °C (lit.)
refractive index n20/D 1.403(lit.)
Fp 153 °F
form liquid
color Colorless to Light yellow to Light red
Specific Gravity1.054
Hydrolytic Sensitivity7: reacts slowly with moisture/water
BRN 1769843
CAS DataBase Reference2182-66-3(CAS DataBase Reference)
NIST Chemistry ReferenceSilanediol, dimethyl-, diacetate(2182-66-3)
EPA Substance Registry SystemSilanediol, dimethyl-, diacetate (2182-66-3)
Safety Information
Hazard Codes C
Risk Statements 34
Safety Statements 26-28-36/37/39-45
RIDADR UN 3265 8/PG 3
WGK Germany 3
10-21
TSCA Yes
HazardClass 3.2
PackingGroup III
HS Code 29319090
MSDS Information
ProviderLanguage
Diacetoxydimethylsilane English
SigmaAldrich English
Diacetoxydimethylsilane Usage And Synthesis
FeaturesDimethyldiacetoxysilane is a clear to yellowish liquid with acrid odor of acetic acid (vinegar). It hydrolyzes in the presence of moisture (acetic acid is released) to form silanols, which can react with themselves to pro-duce siloxanes or bind to inorganic substrates.
Acetoxy silanes are more reactive than alkoxysilanes. Acetoxy silanes are frequently used as one-component mixtures to make RTV-1 silicone sealants. These mixtures have an excess of multi-functional acetoxy silane added to silanol-terminated PDMS, which results in a PDMS chain with acetoxy groups at the ends. When this compound is exposed to moisture some acetoxy groups are hydrolyzed and self-condense or react with other acetoxy and rapid crosslinking takes place. Acetic acid formation is one of the driving forces of this reaction.
Chemical PropertiesColorless or yellowish transparent liquid
Diacetoxydimethylsilane Preparation Products And Raw materials
Methyltriacetoxysilane Diphenyldimethoxysilane 1-Methoxy-2-propyl acetate Diacetoxydimethylsilane Dimethyldimethoxysilane Sodium triacetoxyborohydride Diphenyldiethoxysilane tert-Butyldimethylsilyl chloride Benzoic acid, 4-hydroxy-, diphenylsilylene ester DIMETHYLSILANE Benzoic acid, 4-iodo-, diphenylsilylene ester Ethyl ethoxyacetate Vinyl acetate VINYLMETHYLDIACETOXYSILANE BIS(METHACRYLOXY)DIPHENYLSILANE METHYLPHENYLDIACETOXYSILANE Dichlorodimethylsilane DIPHENYLDIACETOXYSILANE

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