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| | KEMP'S TRIACID Basic information |
| Product Name: | KEMP'S TRIACID | | Synonyms: | 1,3,5-Trimethylcyclohexane-1β,3β,5β-tricarboxylic acid;cis,cis-1,3,5-Trimethyl-1,3,5-cyclohexanetricarboxylic acid;CIS,CIS-1,3,5-TRIMETHYLCYCLOHEXANE-1,3,5-TRICARBOXYLIC ACID;KEMP'S TRIACID;cis,cis-1,3,5-trime.cyclohexane-1,3,5-tricarboxylic acid;1,3,5-Trimethyl-1,3,5-cyclohexanetricarboxylicacid(Kemp'striacid);Aluminum oxide, fused, #200+325 mesh, 99+% metals basis;cis,cis-1,3,5-Trimethyl-1,3,5-cyclohexanetricarboxylic acid (Kemp''s triacid) | | CAS: | 79410-20-1 | | MF: | C12H18O6 | | MW: | 258.27 | | EINECS: | | | Product Categories: | pharmacetical | | Mol File: | 79410-20-1.mol |  |
| | KEMP'S TRIACID Chemical Properties |
| Melting point | 241-243 °C(lit.) | | Boiling point | 364.0±42.0 °C(Predicted) | | density | 1.301±0.06 g/cm3(Predicted) | | storage temp. | 2-8°C | | pka | 4.02±0.50(Predicted) | | BRN | 3557263 | | CAS DataBase Reference | 79410-20-1 |
| | KEMP'S TRIACID Usage And Synthesis |
| Uses | Versatile molecule for molecular recognition studies. Also used to prepare a chiral auxiliary for asymmetric radical addition, allylation, and annulation reactions. | | Purification Methods | Recrystallise the tricarboxylic acid from Me2CO after re-precipitating it several times with mineral acid from aqueous alkaline soltion. The trimethyl ester has m 78-81o. [cf. Kemp J Org Chem 46 5140 1981, Jeong et al. J Am Chem Soc 113 201 1991, Stack et al. J Am Chem Soc 114 7007 1992.] |
| | KEMP'S TRIACID Preparation Products And Raw materials |
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