COBALT(III) FLUORIDE

COBALT(III) FLUORIDE Basic information
Product Name:COBALT(III) FLUORIDE
Synonyms:Cobalt(Ⅲ)fluoride;COBALT FLUORIDE;COBALT FLUORIDE BROWN;COBALTIC FLUORIDE;COBALT(III) FLUORIDE;COBALT TRIFLUORIDE;Cobalt fluoride (CoF3);cobaltfluoride(cof3)
CAS:10026-18-3
MF:CoF3
MW:115.93
EINECS:233-062-4
Product Categories:Inorganic Fluorides;metal halide
Mol File:10026-18-3.mol
COBALT(III) FLUORIDE Structure
COBALT(III) FLUORIDE Chemical Properties
Melting point 927°C
density 3.88 g/mL at 25 °C(lit.)
form Powder
color Light brown
Specific Gravity3.88
Water Solubility Insoluble in water.
Sensitive Hygroscopic
Merck 14,2430
Exposure limitsACGIH: TWA 0.02 mg/m3; TWA 2.5 mg/m3
NIOSH: IDLH 250 mg/m3; TWA 2.5 mg/m3
Stability:hygroscopic
CAS DataBase Reference10026-18-3(CAS DataBase Reference)
EPA Substance Registry SystemCobalt fluoride (CoF3) (10026-18-3)
Safety Information
Hazard Codes C,T,O
Risk Statements 34
Safety Statements 26-36/37/39-45
RIDADR UN 3260 8/PG 2
WGK Germany 3
21
Hazard Note Toxic/Corrosive/Oxidiser
TSCA Yes
HazardClass 5.1
PackingGroup III
HS Code 28261990
MSDS Information
ProviderLanguage
SigmaAldrich English
ACROS English
ALFA English
COBALT(III) FLUORIDE Usage And Synthesis
Chemical Propertiesbrown powder
Chemical PropertiesThe heat of formation is —187 kcal mole-1 and the magnetic moment is 1-60 B.M. at 90°K rising to 2.46 B.M. at 293°K; it is thus a high spin compound but not magnetically dilute.
Anhydrous cobalt(III) fluoride turns dark in the presence of traces of water and reacts violently with the liquid-evolving oxygen. When heated in an inert atmosphere above 350°, cobalt(II) fluoride is formed. It reacts vigorously with many elements, e.g. Al, P, As, S, I, being reduced to cobalt(II) fluoride. It is insoluble in alcohol, ether and benzene and is a useful fluorinating agent in organic chemistry.
Physical propertiesLight brown hexagonal crystal; density 3.88 g/cm3; moisture sensitive; stable in dry air; melts at 927°C; reacts with water.
UsesImportant fluorinating agent, particularly for complete fluorination of hydrocarbons by the Fowler process.
UsesCobalt(III) fluoride is a powerful fluorinating agent.
PreparationCobalt(III) fluoride may be prepared by reaction of elemental fluorine with cobalt(II) fluoride, cobalt(II) chloride or cobalt(III) oxide at 300 to 400°C.
2CoF2 + F2 → 2CoF3
2CoCl2 + 3F2 → 2CoF3 + 2Cl2
It should be stored in a sealed glass ampule, free from moisture.
Electrolytic oxidation of cobalt(II) fluoride in 40% hydrofluoric acid yields hydrated cobalt(III) fluoride, CoF3·3.5H2O (3.5 is the stoichiometric amount of water per CoF3 molecule in the crystal lattice).
HazardStrong irritant to tissue.
Structure and conformationIt forms hexagonal crystals of density 3.89, isomorphous with iron(III) and aluminium(III) fluorides, the cobalt atoms being octahedraily surrounded by fluorine atoms.
COBALT(III) FLUORIDE Preparation Products And Raw materials
Nickel chloride Cobalt sulfate heptahydrate Cobalt(II) hydroxide trisodium nitride Cobaltous nitrate hexahydrate COBALT(II) SULFATE HYDRATE COBALT(II) BROMIDE COBALT(III) OXIDE BLACK COBALT(II) SULFATE HYDRATE Tricobalt tetraoxide Manganese sulfide LITHIUM COBALT(III) OXIDE Triiron tetraoxide Cobalt chloride Cobalt oxide COBALT(III) FLUORIDE Cobalt(II) fluoride Cobalt

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