ChemicalBook Product Catalog Organic Chemistry Heterocyclic Compounds 1-(DIETHOXYMETHYL)IMIDAZOLE

1-(DIETHOXYMETHYL)IMIDAZOLE

1-(DIETHOXYMETHYL)IMIDAZOLE Basic information
Product Name:1-(DIETHOXYMETHYL)IMIDAZOLE
Synonyms:1-(diethoxymethyl)-1H-imidazole;1-(DIETHOXYMETHYL)IMIDAZOLE;1-(Diethoxymethyl)imidazole >=97.0%;1H-Imidazole, 1-(diethoxymethyl)-
CAS:61278-81-7
MF:C8H14N2O2
MW:170.21
EINECS:
Product Categories:Heterocyclic Compounds
Mol File:61278-81-7.mol
1-(DIETHOXYMETHYL)IMIDAZOLE Structure
1-(DIETHOXYMETHYL)IMIDAZOLE Chemical Properties
Boiling point 52 °C(Press: 0.02 Torr)
density 1.041 g/mL at 20 °C (lit.)
refractive index n20/D 1.464
Fp 112℃
storage temp. 2-8°C
pka6.13±0.20(Predicted)
BRN 908482
Safety Information
Hazard Codes Xn
Risk Statements 22-36/37/38
Safety Statements 26
WGK Germany 3
F 10-21
MSDS Information
ProviderLanguage
SigmaAldrich English
1-(DIETHOXYMETHYL)IMIDAZOLE Usage And Synthesis
Uses1-(Diethoxymethyl)imidazole may be used in the preparation of various hydroxy- and amino-functionalized imidazoles, via isoprene-mediated lithiation followed by reaction with an electrophile.
General Description1-(Diethoxymethyl)imidazole is an orthoamide protected imidazole. The dianion reacts selectively at the 2 position 1-(Diethoxymethyl)imidazole is a 1-substituted imidazoles. Isoprene-mediated lithiation of 1-(diethoxymethyl)imidazole, leads to the preparation of the corresponding 2-lithio intermediate, which reacts with different electrophiles to afford 2-functionalised imidazoles.
1-(DIETHOXYMETHYL)IMIDAZOLE Preparation Products And Raw materials
Preparation Products1-(1H-IMIDAZOL-2-YL)-ETHANONE HCL-->1H-Imidazole-2-carboxylic acid-->2-(1H-imidazol-2-yl)propan-2-ol-->2-Chloro-1H-imidazole-->(1H-IMIDAZOL-2-YL)-PHENYL-METHANOL
1-(DIETHOXYMETHYL)IMIDAZOLE
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