2,4-DIAMINOANISOLE

2,4-DIAMINOANISOLE Basic information
Product Name:2,4-DIAMINOANISOLE
Synonyms:pelagoll;p-Methoxy-m-phenylenediamine;4-METHOXY-M-PHENYLENEDIAMINE;4-METHOXY-BENZENE-1,3-DIAMINE;4-METHOXY-1,3-PHENYLENEDIAMINE;3-AMINO-4-METHOXYANILINE;2,4-DIAMINOANISOLE;1,3-Benzenediamine, 4-methoxy-
CAS:615-05-4
MF:C7H10N2O
MW:138.17
EINECS:210-406-1
Product Categories:
Mol File:615-05-4.mol
2,4-DIAMINOANISOLE Structure
2,4-DIAMINOANISOLE Chemical Properties
Melting point 67.5°C
Boiling point 253.57°C (rough estimate)
density 1.1315 (rough estimate)
refractive index 1.5200 (estimate)
solubility Chloroform (Slightly), DMSO (Slightly), Methanol (Very Slightly)
form neat
Colour Index 76050
pka5.19±0.10(Predicted)
BRN 2085522
CAS DataBase Reference615-05-4(CAS DataBase Reference)
IARC2B (Vol. Sup 7, 79) 2001
NIST Chemistry Reference1,3-Benzenediamine, 4-methoxy-(615-05-4)
EPA Substance Registry System2,4-Diaminoanisole (615-05-4)
Safety Information
Hazard Codes T,N
Risk Statements 45-22-51/53-68
Safety Statements 53-45-61
RIDADR 2811
WGK Germany 3
RTECS BZ8580500
HazardClass 6.1(b)
PackingGroup III
Hazardous Substances Data615-05-4(Hazardous Substances Data)
MSDS Information
2,4-DIAMINOANISOLE Usage And Synthesis
Chemical Properties2,4-Diaminoanisole is a needle-like solid.
Uses2,4-Diaminoanisole may be used as an analytical reference standard for the determination of the analyte in:
  • Mainstream waterpipe smoke using liquid chromatography-electrospray ionization-tandem mass spectrometry (LC-ESI-MS/MS).
  • Haircolor products by high performance liquid chromatography (HPLC).

DefinitionChEBI: 2,4-Diaminoanisole is a member of methoxybenzenes.
General DescriptionColorless needles. Primarily used (along with salts such as 2,4-DIAMINOANISOLE sulfate) as a component of hair & fur dye formulations.
Reactivity Profile2,4-DIAMINOANISOLE is incompatible with the following: Strong oxidizers .
Safety ProfileConfirmed carcinogen. Poison by intraperitoneal route. Moderately toxic by ingestion. Experimental reproductive effects. Human mutation data reported. A skin irritant. When heated to decomposition it emits toxic fumes of NOx. See also other diaminoanisole entries.
Potential ExposureThe principal use of 2,4-diamino-ani- sole (and its salts such as the sulfate) as a component of oxidation (permanent) hair and fur dye formulations. Human exposure to 2,4-diaminoanisole sulfate may possibly occur through skin absorption at chemical and dye production facilities, as well as through dermal contact in persons using hair dyes containing the chemical.
ShippingUN2811 Toxic solids, organic, n.o.s., Hazard Class: 6.1; Labels: 6.1-Poisonous materials, Technical Name Required. UN3143 Dyes, solid, toxic, n.o.s. or Dye intermediates, solid, toxic, n.o.s., Hazard Class: 6.1; Labels: 6.1-Poisonous materials, Technical Name Required.
IncompatibilitiesIncompatible with strong oxidizers (chlorates, nitrates, peroxides, permanganates, perchlorates, chlorine, bromine, fluorine, etc.); contact may cause fires or explosions. Keep away from alkaline materials, strong bases, strong acids, oxoacids, and epoxides. The sulfate may react violently with aluminum and magnesium.
Waste DisposalDissolve or mix the material with a combustible solvent and burn in a chemical incinera- tor equipped with an afterburner and scrubber. All federal, state, and local environmental regulations must be observed .
2,4-DIAMINOANISOLE Preparation Products And Raw materials
Preparation Products4,4'-[(4-methoxy-1,3-phenylene)bis(azo)]bisbenzene-1,3-diamine
PARA-DIAMINOANISOLE 3'-Amino-4'-methoxyacetanilide 2,5-DIAMINOANISOLE SULFATE 2,4-DINITROPHENETOLE BIS(2,4-DINITROPHENYL) OXALATE 4-Acetylamino-2-(bis(2-hydroxyethyl)amino)anisole Fast Scarlet RC Base 4-methoxy-1,3-phenylenediamine sulfate hydrate 2-(2,4-Diaminophenoxy)ethanol sulfate N-[3-[(2-Cyanoethyl)ethylamino]-4-methoxyphenyl]acetamide 3-(2,4-DINITROPHENOXY)PYRIDINE 4-TERT-BUTYL-2,6-DIAMINOANISOLE 1-Methoxy-2,4-dinitrobenzene N-(3-amino-4-ethoxyphenyl)acetamide N-(2-methoxy-5-nitrophenyl)acetamide N-(4-ethoxy-3-nitrophenyl)acetamide 2-METHOXY-5-NITROFORMANILIDE 3-(N,N-Diacetoxyethyl)amino-4-methoxyacetanilide

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