ChemicalBook Product Catalog Chemical Reagents Organic reagents Hydrazine p-Anisohydrazide

p-Anisohydrazide

p-Anisohydrazide Basic information
Product Name:p-Anisohydrazide
Synonyms:p-anisohydrazide;P-ANISIC HYDRAZIDE;P-ANISOYLHYDRAZINE;P-METHOXY BENZHYDRAZIDE;4-METHOXYBENZENE-1-CARBOHYDRAZIDE;4-METHOXYBENZOHYDRAZIDE;4-METHOXYBENZHYDRAZIDE;4-METHOXY-BENZOIC ACID HYDRAZIDE
CAS:3290-99-1
MF:C8H10N2O2
MW:166.18
EINECS:221-952-5
Product Categories:Building Blocks;Carbonyl Compounds;Carbonyl Compounds;Hydrazides;Chemical Synthesis;Organic Building Blocks;Aromatic Hydrazides, Hydrazines, Hydrazones and Oximes;Organic Building Blocks
Mol File:3290-99-1.mol
p-Anisohydrazide Structure
p-Anisohydrazide Chemical Properties
Melting point 136-140 °C(lit.)
Boiling point 294.38°C (rough estimate)
density 1.2265 (rough estimate)
refractive index 1.6180 (estimate)
storage temp. Sealed in dry,Room Temperature
pka12.65±0.10(Predicted)
form powder to crystal
color White to Orange to Green
Water Solubility Slightly soluble in water.
BRN 389017
InChIKeyREKQLYUAUXYJSZ-UHFFFAOYSA-N
CAS DataBase Reference3290-99-1(CAS DataBase Reference)
Safety Information
Hazard Codes Xi
Risk Statements 36/37/38
Safety Statements 26-37/39
WGK Germany 3
RTECS BZ4800000
HazardClass IRRITANT
HS Code 2928009090
ToxicityLD50 ivn-mus: 178 mg/kg CSLNX* NX#00894
MSDS Information
ProviderLanguage
SigmaAldrich English
ALFA English
p-Anisohydrazide Usage And Synthesis
Uses4-Methoxybenzhydrazide is used as pharmaceutical intermediates and it is also involved in a variety of organic synthesis.
Uses4-Methoxybenzhydrazide may be used to synthesize:
  • N′-[(E)-5-bromo-2-hydroxy-3-methoxybenzylidene]-4-methoxybenzohydrazide monohydrate
  • 2,5-bis(4-methoxyphenyl)-1,3,4-oxadiazole
  • hydrazone ligands, which readily forms ruthenium(II) hydrazone complexes via reaction with [RuHCl(CO)(PPh3)3]
Synthesis Reference(s)Journal of Medicinal Chemistry, 27, p. 1565, 1984 DOI: 10.1021/jm00378a007
Safety ProfilePoison by intravenous route. Questionable carcinogen with experimental neoplastigenic data. When heated to decomposition it emits toxic fumes of Nox.
p-Anisohydrazide Preparation Products And Raw materials
Preparation ProductsN''-(CHLOROACETYL)-4-METHOXYBENZOHYDRAZIDE-->5-(4-METHOXYPHENYL)-1 3 4-OXADIAZOLE-2-&-->2-(4-methoxyphenyl)-1,3,4-oxadiazole-->4-ALLYL-5-(4-METHOXYPHENYL)-4H-1,2,4-TRIAZOLE-3-THIOL-->4-(5-(4-methoxyphenyl)-1,3,4-oxadiazol-2-yl)benzene-1,2-diamine
3,4,5-TRIMETHOXYBENZHYDRAZIDE 4-PHENOXYBENZHYDRAZIDE p-Anisohydrazide N-(((1,3-DIOXOINDAN-2-YLIDENE)ETHYL)AMINO)(3,4,5-TRIMETHOXYPHENYL)FORMAMIDE 1-(4-METHOXYBENZOYL)-2-(1-NAPHTHOYL)-HYDRAZINE N-(((CYCLOHEXYLAMINO)THIOXOMETHYL)AMINO)(3,4,5-TRIMETHOXYPHENYL)FORMAMIDE 1-((4-(PHENYLMETHOXY)PHENYL)CARBONYL)-4-(3-(TRIFLUOROMETHYL)PHENYL)SEMICARBAZIDE 4-(4-METHOXYPHENYL)-1-(3,4,5-TRIMETHOXYBENZOYL)THIOSEMICARBAZIDE 3,4-DIMETHOXYBENZHYDRAZIDE 3,5-DIIODO-4-METHOXYBENZHYDRAZIDE 4-ETHOXYBENZHYDRAZIDE 3,4-METHYLENEDIOXYBENZHYDRAZIDE 1-((4-(BENZYLOXY)PHENYL)CARBONYL)-4-(4-(TRIFLUOROMETHOXY)PHENYL)SEMICARBAZIDE N'-[(E)-1,3-BENZODIOXOL-5-YLMETHYLIDENE]-1,3-BENZODIOXOLE-5-CARBOHYDRAZIDE VITAS-BB TBB000553 4-(4-CHLOROPHENYL)-1-(3,4,5-TRIMETHOXBENZOYL)THIOSEMICARBAZIDE N'-(6-FLUORO-2-PYRIDINYL)-4-METHOXYBENZENECARBOHYDRAZIDE 3,5-DICHLORO-4-METHOXYBENZENECARBOHYDRAZIDE
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