2-CYCLOHEXEN-1-OL

2-CYCLOHEXEN-1-OL Basic information
Product Name:2-CYCLOHEXEN-1-OL
Synonyms:CYCLOHEX-2-ENOL;2-CYCLOHEXENOL;2-CYCLOHEXEN-1-OL;2-CYCLOHEXENE-1-OL;1-Cyclohexen-3-ol;3-Hydroxycyclohexene;Cyclohexen-3-ol;cyclohex-2-ene-1-ol
CAS:822-67-3
MF:C6H10O
MW:98.14
EINECS:212-501-3
Product Categories:Chiral Alcohols;Alkenes;Cyclic;Organic Building Blocks
Mol File:822-67-3.mol
2-CYCLOHEXEN-1-OL Structure
2-CYCLOHEXEN-1-OL Chemical Properties
Melting point 107-108℃
Boiling point 164-166 °C(lit.)
density 1 g/mL at 25 °C(lit.)
refractive index n20/D 1.487(lit.)
Fp 137 °F
storage temp. Refrigerator, under inert atmosphere
solubility Chloroform (Slightly), Methanol (Slightly)
form Liquid
pka14.70±0.20(Predicted)
color Clear colorless
BRN 1446187
InChIKeyPQANGXXSEABURG-UHFFFAOYSA-N
CAS DataBase Reference822-67-3(CAS DataBase Reference)
EPA Substance Registry System2-Cyclohexen-1-ol (822-67-3)
Safety Information
Risk Statements 36/37/38
Safety Statements 23-24/25
RIDADR UN 1987 3/PG 3
WGK Germany 3
HazardClass 3.2
PackingGroup III
HS Code 29061990
MSDS Information
ProviderLanguage
SigmaAldrich English
2-CYCLOHEXEN-1-OL Usage And Synthesis
Chemical PropertiesClear colorless liquid
Synthesis Reference(s)Tetrahedron Letters, 25, p. 527, 1984 DOI: 10.1016/S0040-4039(00)99928-3
Purification MethodsPurify 2-cyclohexen-1-ol by distillation through a short Vigreux column (p 11). The 2,4-dinitrobenzoyl derivative has m 120.5o, and the phenylurethane has m 107o. [Pedersen et al. Org Synth 48 18 1968, Cook J Chem Soc 1774 1938, Deiding & Hartman J Am Chem Soc 75 3725 1953, Beilstein 6 IV 196.]
2-CYCLOHEXEN-1-OL Preparation Products And Raw materials
Preparation Products2-Cyclohexen-1-one-->Cyclohexene oxide-->Cyclohexene, 3-nitro--->3-BROMOCYCLOHEXENE-->(((4-Methoxycyclohex-3-en-1-yl)oxy)methyl)benzene
RORIDIN A M-3-G HYDRATE 7BETA-HYDROXYCHOLESTEROL (-)-CARVYL PROPIONATE L-CARVYL ACETATE 3-METHYL-2-CYCLOHEXEN-1-OL VERRUCAROL DL-SOBREROL 1-ACETOXY-8-HYDROXY-1,4,4A,9A-TETRAHYDROANTHRAQUINONE BROMOCONDURITOL 5-(1-HYDROXY-2,6,6-TRIMETHYL-4-OXOCYCLOHEX-2-ENYL)-3-METHYLPENTA-2,4-DIENOIC ACID M-6-G TRIFLUOROACETATE-HYDRATE CYTOCHALASIN C TRANS-1,4-CYCLOHEXENEDIOL cis-VERBENOL 4-EPIOXYTETRACYCLINE 2-CYCLOHEXEN-1-ONE DIMETHYLKETAL 1-HYDROXY-4-KETO-2-IONONE

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