Vinyl chloroacetate

Vinyl chloroacetate Basic information
Product Name:Vinyl chloroacetate
Synonyms:CHLOROACETIC ACID VINYL ESTER;VINYL CHLOROACETATE;VINYL CHLOROACETATE, STAB.;Vinylchloroacetate,99%;CHLOROACETICACIDVINYLESTER(STABILIZEDWITHMEHQ);Vinyl Chloroacetate (stabilized with MEHQ);Acetic acid, chloro-, ethenyl ester;Chloroacetic acid vinyl
CAS:2549-51-1
MF:C4H5ClO2
MW:120.53
EINECS:219-834-3
Product Categories:C2 to C5;Carbonyl Compounds;Esters
Mol File:2549-51-1.mol
Vinyl chloroacetate Structure
Vinyl chloroacetate Chemical Properties
Boiling point 37-38°C 16mm
density 1.192 g/mL at 20 °C
vapor pressure 6.973hPa at 20℃
refractive index n20/D 1.444
Fp 51°C
storage temp. 2-8°C
Water Solubility Difficult to mix in water.
BRN 1741679
LogP0.63
CAS DataBase Reference2549-51-1(CAS DataBase Reference)
EPA Substance Registry SystemAcetic acid, 2-chloro-, ethenyl ester (2549-51-1)
Safety Information
Hazard Codes C
Risk Statements 10-20/21/22-34-22
Safety Statements 26-36/37/39-45
RIDADR UN 2589 6.1/PG 2
WGK Germany 3
RTECS AG2850000
8-10-19-23
TSCA Yes
HazardClass 6.1
PackingGroup II
HS Code 29154000
MSDS Information
ProviderLanguage
Chloroacetic acid vinyl ester English
SigmaAldrich English
ALFA English
Vinyl chloroacetate Usage And Synthesis
Chemical PropertiesVinyl chloroacetate is a colorless clear liquid, almost insoluble in water, soluble in ethanol, carbon tetrachloride, ether, dimethylformamide and benzene. Irritating to skin and eyes. Corrosive. Slowly hydrolyzed to produce chloroacetic acid, which has an ecological impact. It can be used as a raw material for making methacrylic fibers with good affinity for acid dyes.
UsesVinyl chloroacetate was used to study the effect of the electron-withdrawing groups on the ligand in a series of bis(acetylacetonate)cobalt(II) derivatives.
General DescriptionVinyl chloroacetate appears as a colorless to light yellow colored liquid. Insoluble in water and denser than water. Contact may irritate skin, eyes and mucous membranes. Toxic by ingestion, inhalation or skin absorption.
Air & Water ReactionsHighly flammable. Insoluble in water.
Reactivity ProfileVinyl chloroacetate reacts with acids to liberate heat. Strong oxidizing acids may cause a vigorous reaction that is sufficiently exothermic to ignite the reaction products. Heat is also generated by the interaction of esters with caustic solutions. Flammable hydrogen is generated by mixing with alkali metals and hydrides.
Health HazardTOXIC; inhalation, ingestion or contact (skin, eyes) with vapors, dusts or substance may cause severe injury, burns or death. Bromoacetates and chloroacetates are extremely irritating/lachrymators. Reaction with water or moist air will release toxic, corrosive or flammable gases. Reaction with water may generate much heat that will increase the concentration of fumes in the air. Fire will produce irritating, corrosive and/or toxic gases. Runoff from fire control or dilution water may be corrosive and/or toxic and cause pollution.
Fire HazardHIGHLY FLAMMABLE: Will be easily ignited by heat, sparks or flames. Vapors form explosive mixtures with air: indoors, outdoors and sewers explosion hazards. Most vapors are heavier than air. They will spread along ground and collect in low or confined areas (sewers, basements, tanks). Vapors may travel to source of ignition and flash back. Substance will react with water (some violently) releasing flammable, toxic or corrosive gases and runoff. Contact with metals may evolve flammable hydrogen gas. Containers may explode when heated or if contaminated with water.
Vinyl chloroacetate Preparation Products And Raw materials
VINYL ESTER RESIN BUTTPARK 60\40-55 VINYL CHLOROACETATE, (CHLOROACETIC ACID VINYL ESTER) AURORA KA-5058 ALLYL CHLORACETATE 3-chlorodihydro-5-methylfuran-2(3H)-one 3,3-dichlorodihydro-5-methylfuran-2(3H)-one 3,3-dichloro-5-hexyldihydrofuran-2(3H)-one 3-CHLORO-PYRAN-2-ONE Vinyl ester resin 5-butyl-3,3-dichlorodihydrofuran-2(3H)-one VINYLGLOVES 3,5-DICHLORO-6-METHYL-1,4-OXAZIN-2-ONE 3,3-dichloro-5-ethyldihydrofuran-2(3H)-one Chloroethylene carbonate vinyl monochloroacetate LUTEINESTER POLY(VINYL ALCOHOL-CO-VINYL CHLOROACETATE)

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