Bis(di-tert-butyl)-4-dimethylaminophenylphosphine

Bis(di-tert-butyl)-4-dimethylaminophenylphosphine Basic information
Use Reaction
Product Name:Bis(di-tert-butyl)-4-dimethylaminophenylphosphine
Synonyms:Bis(di-tert-butyl)-4-dimethylaminophenylphosphine;[(4-Dimethylaminophenyl)]di(tert-butyl)phosphine;[4-(Dimethylamino)phenyl]bis(tert-butyl)phosphine;4,4'-Phosphinediylbis(2,3-di-tert-butyl-N,N-dimethylaniline);N,N-Dimethyl 4-(di(tert-butyl)phosphino)aniline;95% A-taPhos;(4-(N,N-DiMethylaMino)phenyl)di-tert-butyl phosphine,95% A-taPhos;(4-(N,N-DiMethylaMino)phenyl)di-tert-butyl phosphine,95%
CAS:932710-63-9
MF:C16H28NP
MW:265.37
EINECS:
Product Categories:Achiral Phosphine;Aryl Phosphine
Mol File:932710-63-9.mol
Bis(di-tert-butyl)-4-dimethylaminophenylphosphine Structure
Bis(di-tert-butyl)-4-dimethylaminophenylphosphine Chemical Properties
Melting point 57-61°C
Boiling point 349.1±25.0 °C(Predicted)
storage temp. Keep in dark place,Inert atmosphere,Room temperature
solubility soluble in Acetone
pka4.73±0.24(Predicted)
form crystal
color white to light-brown
InChIKeyIQTHEAQKKVAXGV-UHFFFAOYSA-N
CAS DataBase Reference932710-63-9
Safety Information
Hazard Codes Xi
Risk Statements 36/38
Safety Statements 26
WGK Germany 3
TSCA No
HS Code 2931499090
MSDS Information
Bis(di-tert-butyl)-4-dimethylaminophenylphosphine Usage And Synthesis
UseBis(di-tert-butyl)-4-dimethylaminophenylphosphine is an organophosphine compound and can be used as an organophosphine ligand.
Reaction
  1. Ligand used in a highly-active palladium precatalyst for the efficient amination of aryl chloride.
  2. Ligand used in the palladium-catalyzed annulations under microwave enhanced conditions.
Reactions of 932710-63-9
UsesAmphos can be used as an electrophotographic photoreceptor, process cartridge, and image forming electrode.
UsesLigand used to prepare a palladium dichloride catalyst (678740) on treatment with PdCl2(COD). The catalyst effectively cross-couples aryl boronic acids with heteroaryl chlorides.
Bis(di-tert-butyl)-4-dimethylaminophenylphosphine Preparation Products And Raw materials
Raw materialsMagnesium, chloro[4-(dimethylamino)phenyl]--->Di-tert-butylchlorophosphane
Preparation ProductsBIS(DI-TERT-BUTYL(4-DIMETHYLAMINOPHENYL)PHOSPHINE)DICHLOROPALLADIUM
N-Phenylmaleimide N-Methylaniline 1.1'-Binaphthyl-2.2'-diphemyl phosphine N-Phenyl-bis(trifluoromethanesulfonimide) FORMANILIDE 4-Aminodiphenylamine Acetanilide Bis(di-tert-butyl)-4-dimethylaminophenylphosphine DI-TERT-BUTYLPHENYLPHOSPHINE BIS(DI-TERT-BUTYL(4-DIMETHYLAMINOPHENYL)PHOSPHINE)DICHLOROPALLADIUM

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