trans,trans-2,4-Nonadienal

trans,trans-2,4-Nonadienal Basic information
Product Name:trans,trans-2,4-Nonadienal
Synonyms:T2 T4 NONADIENAL;(2E,4E)-2,4-Nonadienal;(E,E)-2,4-nonadien-1 -al;(e,e)-4-nonadienal;(E,E)-nona-2,4-dienal;2,4-trans,trans-Nonadienal;4-Nonadienal,(E,E)-2;nona-trans-2,trans-4-dienal
CAS:5910-87-2
MF:C9H14O
MW:138.21
EINECS:227-629-5
Product Categories:Alphabetical Listings;Flavors and Fragrances;M-N;Aldehydes;C9;Carbonyl Compounds;API intermediates;aldehyde Flavor
Mol File:5910-87-2.mol
trans,trans-2,4-Nonadienal Structure
trans,trans-2,4-Nonadienal Chemical Properties
Boiling point 97-98 °C10 mm Hg(lit.)
density 0.862 g/mL at 25 °C(lit.)
vapor density >1 (vs air)
FEMA 3212 | 2,4-NONADIENAL
refractive index n20/D 1.5207(lit.)
Fp 186 °F
storage temp. 2-8°C
solubility Chloroform (Soluble), DMSO (Slightly), Methanol (Sparingly)
form neat
color Slightly yellow liquid
Odorstrong, fatty, floral odor
Odor Typefatty
Water Solubility INSOLUBLE
JECFA Number1185
Stability:Light Sensitive
LogP2.65
CAS DataBase Reference5910-87-2(CAS DataBase Reference)
NIST Chemistry Reference2,4-Nonadienal, (E,E)-(5910-87-2)
EPA Substance Registry System2,4-Nonadienal, (2E,4E)- (5910-87-2)
Safety Information
Safety Statements 24/25
RIDADR NA 1993 / PGIII
WGK Germany 3
HS Code 29121900
MSDS Information
ProviderLanguage
(E,E)-2,4-Nonadienal English
SigmaAldrich English
ACROS English
trans,trans-2,4-Nonadienal Usage And Synthesis
Chemical Properties2,4-Nonadienal has a strong fatty, floral odor.
Chemical Propertiesclear colorless to yellow liquid
OccurrenceReported found in oxidized flavor of skim milk, in peas by enzymatic formation from lipids, salmon oil, sunflower oil (cis-, trans-, and trans, trans-form), the autooxidation of lard, frozen peas, tomatoes and as a volatile component in fish products. Also reported found in cranberry, asparagus, wheat bread, caviar, Russian cheeses, chicken, cooked beef, mutton, lamb and pork, cognac, filberts, peanuts, popcorn, oatmeal, soybean, olive, beans, mushrooms, Brazil nut, rice and buckwheat.
Usestrans,trans-2,4-Nonadienal is an unsaturated aldehyde that is responsible for the bean odour of soymilk. trans,trans-2,4-Nonadienal has also been identified as a potentially mutagenic substance by inducing oxidative DNA damage.
UsesFood additive.
Aroma threshold valuesDetection: 0.05 ppb; aroma characteristics at 1.0%: green, fatty melon, cucumber and vegetative
Taste threshold valuesTaste characteristics at 2 ppm: green, cucumber with fatty melon and chicken nuances
General Descriptiontrans,trans-2,4-Nonadienal forms adduct in the presence of tetrahydrofuran (THF).
Biochem/physiol ActionsOdor at 1.0%
Safety ProfileWhen heated to decomposition it emits acrid smoke and irritating fumes.
SynthesisBy reduction with LiAlH4 of dienoic acid prepared by the Doebner synthesis, followed by oxidation of the resulting dienol with MnO2 to the corresponding 2,4-dienol
trans,trans-2,4-Nonadienal Preparation Products And Raw materials
Raw materialsManganese dioxide-->Azelaic acid
Preparation Products4-HYDROPEROXY 2-NONENAL
Ethyl-2,4-decadienoate 2,4-DECADIENOIC ACID METHYL ESTER (E,E)-2,4-Dodecadienal DIMETHYL IONONE nonadienal 11-METHOXY-3,7-11-TRIMETHYL-2,4-DODECADIENOIC ACID ISOPROPYL ESTER trans,trans-2,4-Nonadienal PROSTAGLANDIN B1 2-OXO-6-PENTYL-2H-PYRAN-3-CARBOXYLIC ACID, 97 (2R,3S)-1-CARBOXY-4-PENTYL-2,3-DIHYDROXYCYCLOHEXA-4,6-DIENE POTASSIUM SALT METHYL-(5S,6S)-EPOXY-11-OXO-(7E,9E)-UNDECADIENOATE 15D-PGJ2 9-OXO-15S-HYDROXY-PROSTA-5Z,8(12),13E-TRIEN-1-OIC-3,3,4,4-D4 ACID BETA-N-METHYLIONONE trans,trans-2,4-Undecadienal 5-(1-HYDROXY-2,6,6-TRIMETHYL-4-OXOCYCLOHEX-2-EN-1-YL)-3-METHYL-(2E,4E)-PENTADIENOIC ACID CBI-BB ZERO/001679 TRANS,TRANS-2,4-DECADIENAL

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