ALLYL PHENYL SULFIDE

ALLYL PHENYL SULFIDE Basic information
Product Name:ALLYL PHENYL SULFIDE
Synonyms:ALLYL PHENYL SULFIDE;ALLYL PHENYL SULPHIDE;(Allylsulfanyl)benzene;(Allylthio)benzene;3-(Phenylthio)prop-1-ene;3-(Phenylthio)propene;Allyl phenyl thioether;Benzene, (2-propenylthio)-
CAS:5296-64-0
MF:C9H10S
MW:150.24
EINECS:226-142-5
Product Categories:Building Blocks;Chemical Synthesis;Organic Building Blocks;Sulfur Compounds;Organic Building Blocks;Sulfides/Disulfides;Sulfur Compounds
Mol File:5296-64-0.mol
ALLYL PHENYL SULFIDE Structure
ALLYL PHENYL SULFIDE Chemical Properties
Melting point -48--46.5 °C
Boiling point 223-225 °C(lit.)
density 1.024 g/mL at 20 °C(lit.)
refractive index n20/D 1.572
Fp >98°C
form clear liquid
color Colorless to Almost colorless
Sensitive Air Sensitive
BRN 1856940
LogP3.510
CAS DataBase Reference5296-64-0(CAS DataBase Reference)
Safety Information
Hazard Codes Xn
Risk Statements 20/21
Safety Statements 23-36/37/39
RIDADR UN 2810 6.1/PG 2
WGK Germany 3
RTECS WR2400000
13
HS Code 2930.90.2900
HazardClass 6.1(b)
PackingGroup III
MSDS Information
ProviderLanguage
SigmaAldrich English
ALFA English
ALLYL PHENYL SULFIDE Usage And Synthesis
Synthesis Reference(s)Synthesis, p. 625, 1984
Tetrahedron, 47, p. 8621, 1991 DOI: 10.1016/S0040-4020(01)82405-4
Tetrahedron Letters, 20, p. 1481, 1979
Purification MethodsDissolve the sulfide in Et2O, wash with alkali, H2O, dry over CaCl2, evaporate and fractionally distil it, preferably under vacuum. It should not give a precipitate with an alcoholic solution of Pb(OAc)2. [Hurd & Greengard J Am Chem Soc 52 3356 1930, Tarbell & McCall J Am Chem Soc 74 48 1952, Beilstein 6 IV 1479.]
ALLYL PHENYL SULFIDE Preparation Products And Raw materials
Preparation ProductsAllyl phenyl sulfone
2-[(PHENYLTHIO)METHYL]-2-CYCLOPENTEN-1-ONE 2-[(3-PHENYL-2-PROPENYL)SULFANYL]ANILINE 4,6-DICHLORO-2H-1-BENZOTHIINE-3-CARBALDEHYDE (4-CHLOROPHENYL)(DIOXO)(3-PHENYL-2-PROPENYL)-LAMBDA6-SULFANE TRIFLUOPERAZINE DIMALEATE 2-[(4-CHLOROPHENYL)SULFONYL]-4-PHENYL-3-BUTENAL O-METHYLOXIME BIS(P-DIMETHYLAMINOSTYRYL)-P-METHYLPHENYLSULFONYLMETHANE ALLYL PHENYL SULFIDE 2-[(4-CHLOROPHENYL)SULFONYL]-4-PHENYL-3-BUTENAL OXIME 2-[(4-CHLOROPHENYL)SULFONYL]-N,N-DIMETHYL-4-PHENYL-1,3-BUTADIEN-1-AMINE 4-BROMO-3-(((4-CHLOROPHENYL)SULFONYL)METHYL)-2-METHYL-1-PHENYL-3-PYRAZOLIN-5-ONE 1-CHLORO-4-[(3-PHENYL-2-PROPENYL)SULFANYL]BENZENE DIOXO(PHENYL)(3-PHENYL-2-PROPENYL)-LAMBDA6-SULFANE ALLYL PHENYL SULFOXIDE N,N-DIMETHYL-4-PHENYL-2-(PHENYLSULFONYL)-1,3-BUTADIEN-1-AMINE 6-CHLORO-3-[(DIMETHYLAMINO)METHYLENE]-2,3-DIHYDRO-4H-THIOCHROMEN-4-ONE 1,1,3-TRIS(PHENYLTHIO)-1-PROPENE METHALLYLPHENYL SULFIDE

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