2-Bromobutyric acid methyl ester

2-Bromobutyric acid methyl ester Basic information
Product Name:2-Bromobutyric acid methyl ester
Synonyms:2-BROMOBUTYRIC ACID METHYL ESTER;2-BROMO-N-BUTYRIC ACID METHYL ESTER;Methyl-2-bromo butryrate;2-Bromomethylbutyrate;METHYL 2-BROMOBUTYRATE, 1X1ML, MTBE, &;Methyl2-bromobutyrate,97%;(R,S)-2-Bromo-butyric acid methyl ester;2-bromo-butanoic acid methyl ester
CAS:3196-15-4
MF:C5H9BrO2
MW:181.03
EINECS:221-699-0
Product Categories:ester series;500 Series Drinking Water Methods;EPA;Method 552;C2 to C5;Carbonyl Compounds;Esters;bc0001
Mol File:3196-15-4.mol
2-Bromobutyric acid methyl ester Structure
2-Bromobutyric acid methyl ester Chemical Properties
Melting point 116 °C
Boiling point 137-138 °C/50 mmHg (lit.)
density 1.573 g/mL at 25 °C (lit.)
refractive index n20/D 1.452(lit.)
Fp 155 °F
storage temp. Inert atmosphere,Room Temperature
form clear liquid
Specific Gravity1.573
color Colorless to Light yellow
Water Solubility Soluble in alcohol and ether, slightly soluble in water.
BRN 1720826
CAS DataBase Reference3196-15-4(CAS DataBase Reference)
EPA Substance Registry SystemMethyl 2-bromobutyrate (3196-15-4)
Safety Information
Hazard Codes C,Xi,F
Risk Statements 34-38-11
Safety Statements 26-36/37/39-45-24-16-9
RIDADR UN 3265 8/PG 3
WGK Germany 3
19
TSCA Yes
HazardClass 8
PackingGroup III
HS Code 29159000
MSDS Information
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2-Bromobutyric acid methyl ester Usage And Synthesis
Chemical Propertiesclear slightly yellow liquid
UsesMethyl 2-bromobutyrate has been employed as reagent in the synthesis of:
  • racemic indene ester via Reformatsky reaction with 5-methoxy-1-indanone
  • (E)-2-methoxymethylene-butyric acid methyl ester via Reformatsky reaction with α,α-dichloromethyl methyl ether in the presence of zinc dust
  • (E)-2-methoxymethylene-butyryl chloride
UsesMethyl 2-bromobutyrate is used in the synthesis of racemic indene ester via Reformatsky reaction with 5-methoxy-1-indanone. (E)-2-methoxymethylene-butyric acid methyl ester via reformatsky reaction with α,α-dichloromethyl methyl ether in the presence of zinc dust.
2-Bromobutyric acid methyl ester Preparation Products And Raw materials
methyl a-bromobutyrate,Methyl Alpha-Bromobutyrate 1-BROMO-CYCLOBUTANECARBOXYLIC ACID ETHYL ESTER DIMETHYL A-BROMOGLUTARATE Ethyl 2-bromovalerate Methyl 2,4-dibromobutyrate ETHYL 2,3-DIBROMO-3-PHENYLPROPIONATE 2-Bromobutyric acid methyl ester Dimethyl2,2'-Dibromoadipate ETHYL 2-BROMOHEXANOATE ETHYL 2,3-DIBROMOBUTYRATE Ethyl 2-bromotetradecanoate Ethyl 2-bromoheptanoate 4-Acetyl-4-bromobutyric acid methyl ester Ethyl 2-Bromo-4-Phenylbutyrate Ethyl 2,4-dibromobutyrate [S,(+)]-3-Bromobutyric acid methyl ester TERT-BUTYL 2,4-DIBROMOBUTYRATE (S)-(+)-2-AMINO-4-BROMOBUTYRIC ACID METHYL ESTER

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