ChemicalBook Product Catalog Chemical Reagents Organic reagents Nitro compounds 2-Nitrodiphenyl

2-Nitrodiphenyl

2-Nitrodiphenyl Basic information
Product Name:2-Nitrodiphenyl
Synonyms:2-phenylnitrobenzene;2-nitro-bipheny;2-nitro-1’-biphenyl;2-Nitro-1,1'-biphenyl;2-Nitro-1,1’-biphenyl;1’-Biphenyl,2-nitro-1;2-NITRODIPHENYL;2-NITROBIPHENYL
CAS:86-00-0
MF:C12H9NO2
MW:199.21
EINECS:201-646-8
Product Categories:Camphor, etc. (Plasticizer);Functional Materials;Plasticizer
Mol File:86-00-0.mol
2-Nitrodiphenyl Structure
2-Nitrodiphenyl Chemical Properties
Melting point 36-38 °C(lit.)
Boiling point 320 °C
density 1.44
vapor density 5.9 (vs air)
vapor pressure 2 mm Hg ( 140 °C)
refractive index 1.613-1.615
Fp >230 °F
form powder to lump
color White to Yellow to Green
Water Solubility Insoluble
Merck 14,6591
CAS DataBase Reference86-00-0(CAS DataBase Reference)
NIST Chemistry Reference1,1'-Biphenyl, 2-nitro-(86-00-0)
EPA Substance Registry Systemo-Nitrobiphenyl (86-00-0)
Safety Information
Hazard Codes Xn
Risk Statements 20/21/22-40-68-22
Safety Statements 2-7-36-45-36/37
WGK Germany 3
RTECS DV5530000
HS Code 2904.20.5000
MSDS Information
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2-Nitrodiphenyl English
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ACROS English
2-Nitrodiphenyl Usage And Synthesis
Chemical PropertiesCLEAR YELLOW LIQUID AFTER MELTING
UsesPlasticizer for resins, cellulose acetate and nitrate, polystyrenes; fungicide for textiles; wood preservative; dye intermediate.
Synthesis Reference(s)Tetrahedron Letters, 36, p. 6567, 1995 DOI: 10.1016/0040-4039(95)01327-E
General DescriptionGold to tan crystals or brown solid.
Air & Water ReactionsInsoluble in water.
Reactivity ProfileAromatic nitro compounds, such as 2-Nitrodiphenyl, range from slight to strong oxidizing agents. If mixed with reducing agents, including hydrides, sulfides and nitrides, they may begin a vigorous reaction that culminates in a detonation. The aromatic nitro compounds may explode in the presence of a base such as sodium hydroxide or potassium hydroxide even in the presence of water or organic solvents. The explosive tendencies of aromatic nitro compounds are increased by the presence of multiple nitro groups.
Fire Hazard2-Nitrodiphenyl is combustible.
Purification MethodsCrystallise it from EtOH (seeding required). Sublime it under vacuum. [Beilstein 5 H 582, 5 I 273, 5 II 487, 5 III 1750.]
2-Nitrodiphenyl Preparation Products And Raw materials
Preparation Products2-Aminobiphenyl-->2,7-Dibromo-9,9'-spiro-bifluorene-->2,5-DIBROMOBIPHENYL-->N-methylbiphenyl-2-amine-->4'-iodo-2-nitro-1,1'-biphenyl
4-(2-nitrophenyl)aniline 2,5-DINITROFLUORENE Bifendate 9-DICYANOMETHYLENE-2,4,7-TRINITROFLUORENE 2,4,5,7-TETRANITRO-9-FLUORENONE 2-Nitrodiphenyl 4-HYDROXY-2'-NITROBIPHENYL (+)-ALPHA-(2,4,5,7-TETRANITRO-9-FLUORENYLIDENEAMINOXY)PROPIONIC ACID 9-[4-(HEXYLOXY)BENZYLIDENE]-2,4,5,7-TETRANITRO-9H-FLUORENE 2,4'-DINITROBIPHENYL (-)-ALPHA-(2,4,5,7-TETRANITRO-9-FLUORENYLIDENEAMINOXY)PROPIONIC ACID 1-Phenyl-2-nitropropene 2-AMINO-2'-NITRODIPHENYL THIOETHER 2,4,6-TRIPHENYLNITROBENZENE 6,6'-Dinitrodiphenic acid 2,4,7-TRINITRO-9-FLUORENONE (+),(-)-A-2,4,5,7-TETRANITRO-9-FLUORENYLIDENEAMINOOXYPROPIONIC ACID 2,4-DINITRODIPHENYL
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