2-(METHACRYLOYLOXY)ETHYL ACETOACETATE

2-(METHACRYLOYLOXY)ETHYL ACETOACETATE Basic information
Product Name:2-(METHACRYLOYLOXY)ETHYL ACETOACETATE
Synonyms:3-oxo-butanoicaci2-[(2-methyl-1-oxo-2-propenyl)oxy]ethylester;2-(Methacryloyloxy)ethyl acetoacetate,(2-Acetoacetoxy)ethyl methacrylate, AAEM, Ethylene glycol monoacetoacetate monomethacrylate, Lonzamon AAMEA PQ;2-(METHACRYLOYLOXY)E;Monomer AAEMA;ACETOACETIC ACID 2-(METHACRYLOYLOXY)ETHYL ESTER;ACETOACETOXY ETHYL 2-METHYLACRYLATE;ACETOACETOXYETHYL METHACRYLATE;AAEM
CAS:21282-97-3
MF:C10H14O5
MW:214.22
EINECS:244-311-1
Product Categories:monomer
Mol File:21282-97-3.mol
2-(METHACRYLOYLOXY)ETHYL ACETOACETATE Structure
2-(METHACRYLOYLOXY)ETHYL ACETOACETATE Chemical Properties
Melting point <25 °C
Boiling point 100 °C/0.8 mmHg (lit.)
density 1.122 g/mL at 25 °C (lit.)
vapor pressure 0.24Pa at 25℃
refractive index n20/D 1.456
Fp >230 °F
solubility Insoluble in water
pka10.16±0.46(Predicted)
form clear liquid
color Light yellow to Yellow to Orange
Specific Gravity1.122
Water Solubility 18.5g/L at 25℃
BRN 2099809
LogP0.9 at 25℃
CAS DataBase Reference21282-97-3(CAS DataBase Reference)
EPA Substance Registry System2-[Methacryloyloxy]ethyl acetoacetate (21282-97-3)
Safety Information
Hazard Codes T,Xi
Risk Statements 36/37/38-43
Safety Statements 26-36/37-45-36
RIDADR UN 2810 6.1/PG 3
WGK Germany 3
RTECS AK5600000
HS Code 29189990
MSDS Information
ProviderLanguage
SigmaAldrich English
ACROS English
2-(METHACRYLOYLOXY)ETHYL ACETOACETATE Usage And Synthesis
Chemical PropertiesClear liquid.
UsesLONZAMON(R) AAEMA is a special methacrylic ester monomer with a reactive methylene group. It is suitable as comonomer for adhesives and coatings as well as copolymer for emulsion polymerisation.
Uses2-(Methacryloyloxy)ethyl acetoacetate is a methylene active compound that may be used in the synthesis of 2-(methacryloyloxy)ethyl 6-methyl-2-oxo-4-phenyl-1,2,3,4- tetrahydropyrimidine-5-carboxylate. It may be used as a polymerizable chelating agent for metal alkoxides to form polymerizable oxide precursors.
Flammability and ExplosibilityNonflammable
2-(METHACRYLOYLOXY)ETHYL ACETOACETATE Preparation Products And Raw materials
Raw materialsEthyl acetoacetate-->2-Hydroxyethyl methacrylate-->2,2,6-Trimethyl-4H-1,3-dioxin-4-one
Ethyl acetoacetate tert-Butyl acetoacetate 2-(Dimethylamino)ethyl methacrylate 2-Isocyanatoethyl methacrylate NA Methyl acetoacetate (2-Propenyl) 3-oxobutanoate Ethylene glycol Isobutyl acetoacetate 2-Methoxyethyl acetoacetate 2-N-BUTOXYETHYL METHACRYLATE 2-ETHOXYETHYL METHACRYLATE 2-BUTOXYETHYL ACRYLATE 2-Methoxyethyl methacrylate 2-(METHACRYLOYLOXY)ETHYL ACETOACETATE 2-Hydroxyethyl methacrylate 2-(ACRYLOYLOXY)ETHYL ACETOACETATE 2-Hydroxyethyl acrylate

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