METHANESULFONYL FLUORIDE

METHANESULFONYL FLUORIDE Basic information
Product Name:METHANESULFONYL FLUORIDE
Synonyms:METHANESULPHONYL FLUORIDE;METHANESULFONYL FLUORIDE;fluoromethylsulfone;Fumette;fumette[qr];mesylfluoride;methanesulphonylfluoride[qr];MSF
CAS:558-25-8
MF:CH3FO2S
MW:98.1
EINECS:209-192-2
Product Categories:Organic Building Blocks;Sulfonyl Halides;Sulfur Compounds
Mol File:558-25-8.mol
METHANESULFONYL FLUORIDE Structure
METHANESULFONYL FLUORIDE Chemical Properties
Boiling point 123-124 °C(lit.)
density 1.427 g/mL at 25 °C(lit.)
refractive index 1.360
Sensitive Hygroscopic
CAS DataBase Reference558-25-8(CAS DataBase Reference)
EPA Substance Registry SystemMethanesulfonyl fluoride (558-25-8)
Safety Information
Hazard Codes T+,C,T
Risk Statements 23-28-34
Safety Statements 23-26-36/37/39-45
RIDADR UN 3389 6.1/PG 1
WGK Germany 3
RTECS PB2975000
Hazard Note Corrosive/Hygroscopic
TSCA T
HazardClass 6.1(a)
PackingGroup I
Hazardous Substances Data558-25-8(Hazardous Substances Data)
MSDS Information
ProviderLanguage
SigmaAldrich English
METHANESULFONYL FLUORIDE Usage And Synthesis
Chemical Propertiesclear colorless to yellow liquid
General DescriptionLiquid.
Air & Water ReactionsOn contact with moisture METHANESULFONYL FLUORIDE produces highly corrosive and toxic fumes of hydrogen fluoride gas.
Reactivity ProfileMETHANESULFONYL FLUORIDE is corrosive, toxic liquid. Vigorous reaction with water, steam, alkali. A dangerous storage hazard. On contact with moisture METHANESULFONYL FLUORIDE produces highly corrosive and toxic fumes of hydrogen fluoride gas. When heated to decomposition METHANESULFONYL FLUORIDE emits toxic fumes of fluoride, and oxides of sulfur [M. K.]. May react vigorously or explosively if mixed with diisopropyl ether or other ethers in the presence of trace amounts of metal salts [J. Haz. Mat., 1981, 4, 291].
Health HazardHighly toxic when inhaled.
Fire HazardWhen heated to decomposition, METHANESULFONYL FLUORIDE emits very toxic fumes of fluorides and sulfur oxides.
METHANESULFONYL FLUORIDE Preparation Products And Raw materials
3-AMINO-4-CHLOROBENZENESULFONYL FLUORIDE 3-(FLUOROSULFONYL)BENZOIC ACID P-TOLUENESULFONYL FLUORIDE METHANESULFONYL FLUORIDE 4-NITROBENZENESULFONYL FLUORIDE Nonafluorobutanesulfonyl fluoride 3-AMINOBENZENESULFONYL FLUORIDE HYDROCHLORIDE Perfluoro-1-octanesulfonyl fluoride 4-(FLUOROSULFONYL)BENZOYL CHLORIDE Sulfanilyl fluoride 4-FLUOROSULFONYL-1-HYDROXY-2-NAPHTHOIC ACID 2-CHLORO-5-(FLUOROSULFONYL)BENZOIC ACID 3-NITROBENZENESULPHONYL FLUORIDE 97 BENZENESULFONYL FLUORIDE 4-METHOXYMETANILYL FLUORIDE 4-(FLUOROSULFONYL)BENZOIC ACID Phenylmethylsulfonyl fluoride 2-NITRO-BENZENESULFONYL FLUORIDE

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