2-Fluoro-3-methylpyridine

2-Fluoro-3-methylpyridine Basic information
Product Name:2-Fluoro-3-methylpyridine
Synonyms:2-FLUORO-3-PICOLINE;2-FLUORO-3-METHYLPYRIDINE;2-FLUORO-3-METHYLPYRIDINE 97%;2-FLUORO-3-METHYLPYRIDINE (2-FLUORO-3-PICOLINE);2-fluoro-3-methypyridine;2-Fluoro-3-methyl pyridine ,97%;2-Fluoro-3-picoline,98%;2-Fluoro-3-methylpyridine98%
CAS:2369-18-8
MF:C6H6FN
MW:111.12
EINECS:624-901-9
Product Categories:blocks;FluoroCompounds;Pyridines;Pyridine;Pyridines, Pyrimidines, Purines and Pteredines;Pyridine series;Fluorin-contained pyridine series;Fluoropyridines;Halopyridines;Boronic Acid;Fluorine series
Mol File:2369-18-8.mol
2-Fluoro-3-methylpyridine Structure
2-Fluoro-3-methylpyridine Chemical Properties
Boiling point 154-155 °C (lit.)
density 1.098 g/mL at 25 °C (lit.)
refractive index n20/D 1.476(lit.)
Fp 119 °F
storage temp. Inert atmosphere,2-8°C
pka-0.14±0.10(Predicted)
form clear liquid
Specific Gravity1.098
color Colorless to Light orange to Yellow
BRN 1877
CAS DataBase Reference2369-18-8(CAS DataBase Reference)
Safety Information
Hazard Codes Xi,F,Xn
Risk Statements 10-36/37/38-20/21/22-1020/21/2236/37/38
Safety Statements 26-36-36/37/39-16-16 26 36/37/39
RIDADR UN 1993 3/PG 3
WGK Germany 3
Hazard Note Irritant
HazardClass IRRITANT, FLAMMABLE
PackingGroup 
HS Code 29333990
MSDS Information
ProviderLanguage
ACROS English
SigmaAldrich English
ALFA English
2-Fluoro-3-methylpyridine Usage And Synthesis
Chemical Propertiesclear colorless to light yellow liquid
Uses2-Fluoro-3-methylpyridine may be used in the preparation of:
  • 2-phenyl-3-methylpyridine
  • 2-(4-chlorophenyl)-3-methylpyridine
  • 2-(4-fluorophenyl)-3-methylpyridine
  • 2-fluoronicotinic acid

General Description2-Fluoro-3-methylpyridine, also known as 2-fluoro-3-picoline, can be prepared by reacting 2-amino-3-methylpyridine and 40% fluoroboric acid.2 The signs of the long range coupling constants of 2-fluoro-3-methylpyridine have been obtained by double and triple resonance techniques.
2-Fluoro-3-methylpyridine Preparation Products And Raw materials
Preparation Products(3-METHYL-PYRIDIN-2-YL)-HYDRAZINE-->2-Fluoro-5-methylpyridine
2-Fluoro-3-nitropyridine 5-CHLORO-2-FLUORO-3-METHYLPYRIDINE 1,3-DIMETHYL-2-FLUOROPYRIDINIUM TOLUENE-4-SULFONATE Fluorine 2-Fluoropyridine 2-FLUORO-4-IODONICOTINIC ACID 2-Fluoro-3-methylpyridine 2-Chloro-5-chloromethylpyridine 1-(2-Fluoro-3-(2-propenyl)-4-pyridinyl)-1-propanone 2-FLUORO-3-FORMYLPYRIDINE 4-Methylpyridine 6-fluoropyridoxal 2-Fluoronicotinic acid 3-Picoline Azamethiphos Flupirtine 2,6-Lutidine 2,4,6-Collidine

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