1,8-Diaminonaphthalene

1,8-Diaminonaphthalene Basic information
Product Name:1,8-Diaminonaphthalene
Synonyms:1,8-Diaminonaphthalene (1,8-Naphthalene diamine);1,8-DIAMINONAPHTHALONE;1.8-DIAMINA-NAPTHALENE 99.6+%;1,8-Diaminonaphthalene,99%;1,8-Diaminonaphthalene,90%,tech.;1,8-Diaminonaphthale;8-Diaminonaphthalene;Naphthalene-1,8-diamine 99%
CAS:479-27-6
MF:C10H10N2
MW:158.2
EINECS:207-529-8
Product Categories:Building Blocks;Chemical Synthesis;Organics;Nitrogen Compounds;Organic Building Blocks;Polyamines;Intermediates of Dyes and Pigments;Benzene derivatives
Mol File:479-27-6.mol
1,8-Diaminonaphthalene Structure
1,8-Diaminonaphthalene Chemical Properties
Melting point 60-65 °C (lit.)
Boiling point 205 °C/12 mmHg (lit.)
density 1.1265
vapor pressure 0.011Pa at 25℃
refractive index 1.6829
Fp 205°C/12mm
storage temp. Store below +30°C.
solubility methanol: soluble
pka4.46±0.10(Predicted)
form Chunks or Crystalline Mass
color Grayish-red to gray or dark brown
Water Solubility slightly soluble
Merck 14,6372
BRN 742841
Stability:Air Sensitive
InChIKeyYFOOEYJGMMJJLS-UHFFFAOYSA-N
LogP1.335
CAS DataBase Reference479-27-6(CAS DataBase Reference)
NIST Chemistry Reference1,8-Naphthalenediamine(479-27-6)
EPA Substance Registry System1,8-Naphthalenediamine (479-27-6)
Safety Information
Hazard Codes Xn,Xi
Risk Statements 22-40-43-36/37/38
Safety Statements 36/37-36/37/39-26-24-36
RIDADR 2811
WGK Germany 3
8
Hazard Note Irritant
TSCA Yes
HS Code 29215940
ToxicityLD50 orally in Rabbit: 800 mg/kg
MSDS Information
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1,8-Diaminonaphthalene Usage And Synthesis
Chemical PropertiesOff white powder
UsesLubricating-oil antioxidant, analytical reagent
Uses1,8-Diaminonaphthalene is an important raw material and intermediate used in organic synthesis, pharmaceuticals and agrochemicals.
Flammability and ExplosibilityNonflammable
Purification MethodsCrystallise 1,8-diaminonaphthalene from water or aqueous EtOH, and sublime it in a vacuum. The N,N'-dimethyl derivative [20734-56-9] has m 103-104o and pK2 5 5.61, the N,N,N'-trimethyl-derivative [20734-57-0] has m 29-30o and pK2 5 6.43. [Hodgson et al. J Chem Soc 202 1945, Beilstein 13 IV 344.]
4,4'-Diaminodiphenylsulfone 5,6-DIAMINOACENAPHTHENE 2-Naphthylamine 5,6-DINITROACENAPHTHENE 6,7-DINITRO-BENZO[DE]ISOCHROMENE-1,3-DIONE 1,8-Diaminonaphthalene 2,3-DIAMINOTOLUENE N,N,N',N'-TETRAMETHYL-1,8-DIAMINONAPHTHALENE Mordant Black 38 Solvent Red 179 2-AMINOPERIMIDINE HYDROBROMIDE HYDRATE RARECHEM AQ NN 0313 2-AMINOPERIMIDINE HYDROBROMIDE 2-AMINOPERIMIDINE HYDROCHLORIDE 1H-Perimidine, 1-methyl- (9CI) 1,8-Dinitronaphthalene Iminodiacetonitrile N,N-Dimethyl-1,4-phenylenediamine

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