Butyl glycidyl ether

Butyl glycidyl ether Basic information
Product Name:Butyl glycidyl ether
Synonyms:Butyl 2,3-epoxypropyl ether~Glycidol butyl ether;n-Butylglycidylether,95%;Butyl gylcidyl ether.;1-butoxy-2,3-epoxy-propan;2,3-Epoxypropylbutylbutylether;3-Butoxy-1,2-epoxypropane;Ageflex bge;ageflexbge
CAS:2426-08-6
MF:C7H14O2
MW:130.18
EINECS:219-376-4
Product Categories:Oxiranes;Simple 3-Membered Ring Compounds
Mol File:2426-08-6.mol
Butyl glycidyl ether Structure
Butyl glycidyl ether Chemical Properties
Melting point 59 °C
Boiling point 164-166 °C(lit.)
density 0.91 g/mL at 25 °C(lit.)
vapor pressure 5 hPa (20 °C)
refractive index n20/D 1.418(lit.)
Fp 132 °F
storage temp. Store below +30°C.
solubility 20g/l
form Liquid
color Clear colorless
Water Solubility 2 g/100 mL
Sensitive Moisture Sensitive
BRN 103668
Exposure limitsACGIH: TWA 3 ppm (Skin)
OSHA: TWA 50 ppm(270 mg/m3)
NIOSH: IDLH 250 ppm; Ceiling 5.6 ppm(30 mg/m3)
Stability:Stable. May form explosive peroxides on contact with air. Store under inert gas.
LogP0.63 at 25℃
CAS DataBase Reference2426-08-6(CAS DataBase Reference)
NIST Chemistry ReferenceOxirane, (butoxymethyl)-(2426-08-6)
IARC2B (Vol. 125)
EPA Substance Registry Systemn-Butyl glycidyl ether (2426-08-6)
Safety Information
Hazard Codes Xn,T
Risk Statements 10-20/22-37-40-43-52/53-68-20/21/22-45-36/37/38-23/24/25
Safety Statements 24/25-36/37-61-45-53-26
RIDADR UN 3271 3/PG 3
WGK Germany 2
RTECS TX4200000
9-21
Autoignition Temperature215 °C
TSCA Yes
HazardClass 3
PackingGroup III
HS Code 29109000
Hazardous Substances Data2426-08-6(Hazardous Substances Data)
ToxicityLD50 orally in Rabbit: 1660 mg/kg LD50 dermal Rabbit 2520 mg/kg
IDLA250 ppm
MSDS Information
ProviderLanguage
1,2-Epoxy-3-butoxypropane English
SigmaAldrich English
ALFA English
Butyl glycidyl ether Usage And Synthesis
Descriptionn-Butyl glycidyl ether is a reactive diluent used to reduce viscosity of epoxy res ins Bisphenol A type.
Chemical Propertiescolourless liquid
Chemical Propertiesn-Butyl glycidyl ether is a colorless liquid with slight irritating odor.
UsesViscosity-reducing agent, acid acceptor for solvents, chemical intermediate
UsesUses include the roles of viscosity-reducing agent for easier handling of conventional epoxy resins, acid acceptor for stabilizing chlorinated solvents, and chemical intermediate. Some curing agents may produce hazardous polymerizations in large quantities.
Production Methodsn-Butyl glycidyl ether (BGE) is made by the condensation of n-butyl alcohol and epichlorohydrin with subsequent dehydrochlorination with caustic to form the epoxy ring.
General DescriptionColorless to pale yellow liquid with a strong, slightly unpleasant odor. Flash point approximately 164°F. Denser than water. Vapors are heavier than air. Vapors may irritate the nose, throat and respiratory tract. Ingestion or inhalation may cause central nervous system depression. Liquid contact may severely irritate the eyes and skin. Prolonged contact with the skin may cause defatting and drying.
Air & Water ReactionsHighly flammable. Butyl glycidyl ether may be sensitive to prolonged exposure to air, may form explosive peroxide in contact with air.
Reactivity ProfileButyl glycidyl ether, an ether, can act as a base. They form salts with strong acids and addition complexes with Lewis acids. The complex between diethyl ether and boron trifluoride is an example. Ethers may react violently with strong oxidizing agents. In other reactions, which typically involve the breaking of the carbon-oxygen bond, ethers are relatively inert.
HazardA mild skin and eye irritant. Sensitization and reproduction effects.
Health HazardExposure can cause mild irritation of skin, eyes, nose, and respiratory tract. Chronic exposure may cause inflammation and sensitization of the skin.
Flammability and ExplosibilityFlammable
Contact allergensA reactive diluent used to reduce viscosity of epoxy resins Bisphenol A type.
Safety ProfileSuspected Carcinogen. Moderately toxic by ingestion, skin contact, and inuaperitoneal routes. Mildly toxic by inhalation. An experimental teratogen. Mutation data reported. A sktn and severe eye irritant. See also ETHERS. When heated to decomposition it emits acrid and irritating fumes.
Potential ExposureNIOSH has estimated human exposures @ 18,000. Used as reactive diluent for epoxy resins, flooring, laminating, and electrical; and as a stabilizer, viscosity-reducing agent, as acid acceptor for solvents; and as a chemical intermediate
CarcinogenicityBGE was mutagenic in bacterial assays, and DNA damage was induced in human cells in vitro.
ShippingUN1993 Flammable liquids, n.o.s., Hazard Class: 3; Labels: 3—Flammable liquid, Technical Name Required
IncompatibilitiesMay form explosive mixture with air. Air and light form unstable and explosive peroxides. Contact with strong oxidizers may cause fire and explosions. Contact with strong caustics may cause polymerization. Attacks some plastics and rubber
Waste DisposalDissolve or mix the material with a combustible solvent and burn in a chemical incinerator equipped with an afterburner and scrubber. All federal, state, and local environmental regulations must be observed.
Glycerol triglycidyl ether Benzenamine,4,4'-methylenebis-,reaction products with butyl glycidyl ether,Benzenamine, 4,4'-methylenebis-, reaction products with butyl glycidyl ether S-(+)-TERT-BUTYL GLYCIDYL ETHER Cyhalofop-butyl Resin epoxy EPOXY 3,9-bis(3-Aminopropyl)-2,4,8,10-tetroxaspiro[5.5]undecane, n-butyl glycidyl ether, thiourea adduct Allyloxypolyethyleneglycol Ethylene glycol diglycidyl ether Buprofezin 1,2,3-PROPANETRIOL GLYCIDYL ETHER 1,4-Bis((2,3-epoxypropoxy)methyl)cyclohexane 2-Ethylhexyl glycidyl ether Bisphenol S diallyl ether BENZYL GLYCIDYL ETHER LAURYL GLYCIDYL ETHER DIGLYCIDYL ETHER Diafenthiuron

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