ChemicalBook Product Catalog Organic Chemistry Amides Naphthenic amines derivatives 2-Methyl-4-methoxybenzenamine

2-Methyl-4-methoxybenzenamine

2-Methyl-4-methoxybenzenamine Basic information
Product Name:2-Methyl-4-methoxybenzenamine
Synonyms:AKOS 91136;6-AMINO-3-METHOXYTOLUENE;4-METHOXY-O-TOLUIDINE;3-METHYL-4-AMINOANISOLE;2-METHYL-P-ANISIDINE;2-METHYL-4-METHOXYBENZENAMINE;1-AMINO-4-METHOXY-2-METHYLBENZENE;M-CRESIDINE
CAS:102-50-1
MF:C8H11NO
MW:137.18
EINECS:203-036-7
Product Categories:Amines and Anilines;Intermediates of Dyes and Pigments;Amines;Building Blocks;C8 to C9;Chemical Synthesis;Nitrogen Compounds;Organic Building Blocks
Mol File:102-50-1.mol
2-Methyl-4-methoxybenzenamine Structure
2-Methyl-4-methoxybenzenamine Chemical Properties
Melting point 13-14 °C(lit.)
Boiling point 248-249 °C(lit.)
density 1.065 g/mL at 25 °C(lit.)
refractive index n20/D 1.565(lit.)
Fp >230 °F
storage temp. Keep in dark place,Sealed in dry,Room Temperature
solubility Acetonitrile (Slightly), Chloroform (Slightly), DMSO, Methanol (Slightly)
form Oil
pka5.05±0.10(Predicted)
color Light Brown to Very Dark Red
Water Solubility insoluble, <0.1 g/100 mL at 21.5 ºC
BRN 774727
Stability:Stable. May be light or air-sensitive. Combustible. Incompatible with acids, strong oxidizing agents.
InChIKeyCDGNLUSBENXDGG-UHFFFAOYSA-N
CAS DataBase Reference102-50-1(CAS DataBase Reference)
IARC3 (Vol. 27, Sup 7) 1987
NIST Chemistry ReferenceBenzenamine, 4-methoxy-2-methyl-(102-50-1)
EPA Substance Registry Systemm-Cresidine (102-50-1)
Safety Information
Hazard Codes Xi,Xn,T
Risk Statements 36/37/38-40-45
Safety Statements 26-36/37/39-53-45
RIDADR 2810
WGK Germany 3
RTECS BZ6730000
TSCA Yes
HazardClass 6.1
PackingGroup III
HS Code 29222990
Hazardous Substances Data102-50-1(Hazardous Substances Data)
MSDS Information
ProviderLanguage
2-Methyl-4-methoxybenzenamine English
SigmaAldrich English
ACROS English
ALFA English
2-Methyl-4-methoxybenzenamine Usage And Synthesis
Chemical Propertiesbrick red crystals or liquid
Uses4-Methoxy-2-methylaniline is a reagent used in organic synthesis of more complex compounds that have a more specific function. For example, enzyme inhibitors.
DefinitionChEBI: Meta-Cresidine is a member of methoxybenzenes.
General DescriptionCrystals or brick red liquid.
Air & Water ReactionsSensitive to prolonged exposure to air and light. Insoluble in water.
Reactivity Profile2-Methyl-4-methoxybenzenamine neutralizes acids in weakly exothermic reactions to form salts plus water. May be incompatible with isocyanates, halogenated organics, peroxides, phenols (acidic), epoxides, anhydrides, and acid halides. May generate hydrogen, a flammable gas, in combination with strong reducing agents such as hydrides. Reacts with oxidizing agents .
Health HazardACUTE/CHRONIC HAZARDS: 2-Methyl-4-methoxybenzenamine is a local irritant. When heated to decomposition it emits toxic fumes of NOx. 2-Methyl-4-methoxybenzenamine is an experimental animal carcinogen.
Fire Hazard2-Methyl-4-methoxybenzenamine is probably combustible.
Safety ProfileSuspected carcinogen with experimental carcinogenic and tumorigenic data. Mutation data reported. When heated to decomposition it emits toxic fumes of NOx.
3-Dimethylaminoanisole AKOS AU36-M255 ETHYL 4,5-DIMETHOXY-2-NITROBENZOATE 2-Methyl-4-methoxybenzenamine 2-METHOXY-N-METHYANILINE N-[(3,5-Di(trimethylsilyl)-1-pyrazolin-3-yl)methyl]-4-methoxybenzenamine Benzenamine, 2-fluoro-6-methoxy-4-methyl- (9CI) N-Methyl-3-methoxybenzenamine 3-Methoxy-2-methylaniline Methyl 2-amino-3,4,5-trimethoxybenzoate D-ribo-Hexanoic acid, 3-deoxy-, γ-lactone 3-Amino-5-methylisoxazole 2-Methyl-4-methoxyaniline(HCl) 2-Amino-5-methoxybenzoic acid 2,3-DIMETHYL-4-NITROANISOLE 6-ethoxy-1,2,3,4-tetrahydro-2,2,4-trimethylquinoline BRUCINE SULFATE 4,5-DIMETHOXY-2-NITROBENZYL ALCOHOL
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