2-Ethylhexyl acetate

2-Ethylhexyl acetate Basic information
Product Name:2-Ethylhexyl acetate
Synonyms:beta-ethylhexylacetate;Ethyl hexyl acetate;Ethyl(2)-hexyl acetate;ethylhexylacetate;ethylhexylacetate(non-specificname);femanumber2806;2-Ethylhexyl acetate 99%;2-Octyl acetate 99%
CAS:103-09-3
MF:C10H20O2
MW:172.26
EINECS:203-079-1
Product Categories:Alphabetical Listings;E-F;Flavors and Fragrances;ACS and Reagent Grade Solvents;Amber Glass Bottles;Carbon Steel Flex-Spout Cans;ReagentPlus;ReagentPlus Solvent Grade Products;Semi-Bulk Solvents;Solvent Bottles;Solvent by Application;Solvent Packaging Options;Solvents
Mol File:103-09-3.mol
2-Ethylhexyl acetate Structure
2-Ethylhexyl acetate Chemical Properties
Melting point −92 °C(lit.)
Boiling point 199 °C(lit.)
density 0.87 g/mL at 25 °C(lit.)
vapor pressure 0.28 hPa (20 °C)
refractive index n20/D 1.418(lit.)
Fp 185 °F
storage temp. Store below +30°C.
solubility water: slightly soluble0.0039 g/L
form Liquid
color Clear colorless
Odorat 10.00 % in dipropylene glycol. earthy herbal humus undergrowth
Odor Typeearthy
explosive limit0.76-8.14%(V)
Water Solubility 3.9mg/L at 20℃
Merck 14,6763
JECFA Number130
BRN 1758321
InChIKeyWOYWLLHHWAMFCB-UHFFFAOYSA-N
LogP4.2 at 25℃
CAS DataBase Reference103-09-3(CAS DataBase Reference)
NIST Chemistry ReferenceAcetic acid, 2-ethylhexyl ester(103-09-3)
EPA Substance Registry SystemAcetic acid, 2-ethylhexyl ester (103-09-3)
Safety Information
Hazard Codes Xi
Risk Statements 36/37/38-38
Safety Statements 26-36
WGK Germany 1
RTECS AH5600000
Autoignition Temperature268 °C
TSCA Yes
HS Code 29153990
Hazardous Substances Data103-09-3(Hazardous Substances Data)
ToxicityLD50 orally in rats: 3.0 g/kg (Smyth, Carpenter)
MSDS Information
ProviderLanguage
2-Ethylhexyl acetate English
SigmaAldrich English
ACROS English
ALFA English
2-Ethylhexyl acetate Usage And Synthesis
Chemical Propertiesclear colorless liquid
UsesSolvent for nitrocellulose, some resins, waxes, and oils.
DefinitionChEBI: An acetate ester that is hexyl acetate substituted by an ethyl group at position 2.
Synthesis Reference(s)Synthetic Communications, 20, p. 125, 1990 DOI: 10.1080/00397919008054623
Tetrahedron Letters, 23, p. 5407, 1982 DOI: 10.1016/0040-4039(82)80142-1
General DescriptionA water-white liquid. Insoluble in water and is less dense than water. Flash point 180°F. Used as a solvent and in perfumes. Liquid or vapors may irritate skin and eyes. Vapors have a fruity, pleasant odor.
Air & Water ReactionsInsoluble in water.
Reactivity Profile2-Ethylhexyl acetate is an ester. Esters react with acids to liberate heat along with alcohols and acids. Strong oxidizing acids may cause a vigorous reaction that is sufficiently exothermic to ignite the reaction products. Heat is also generated by the interaction of esters with caustic solutions. Flammable hydrogen is generated by mixing esters with alkali metals and hydrides. Contact with strong oxidizers may cause vigorous reaction [USCG, 1999].
Health HazardProlonged skin contact may cause irritation.
Fire HazardSpecial Hazards of Combustion Products: Irritating vapors and toxic gases, such as carbon monoxide, may be formed when involved in fire.
Flammability and ExplosibilityNonflammable
Safety ProfileModerately toxic by ingestion. Askin and eye irritant. Flammable when exposed to heat orflame; can react with oxidizing materials. To fight fire, usefoam, CO2, dry chemical. When heated to decompositionit emits acrid smoke and irritating fumes.
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