TRIS(1,1,1,3,3,3-HEXAFLUORO-2-PROPYL) PHOSPHITE

TRIS(1,1,1,3,3,3-HEXAFLUORO-2-PROPYL) PHOSPHITE Basic information
Product Name:TRIS(1,1,1,3,3,3-HEXAFLUORO-2-PROPYL) PHOSPHITE
Synonyms:Tris(1,1,1,3,3,3-hexafluoro-2-propyl) phosphite 98%;TRIS(1,1,1,3,3,3-HEXAFLUORO-2-PROPYL) PHOSPHITE;Tris(1,1,1,3,3,3-hexafluoro-2-propoxy)phosphite;tris(2h-perfluoro-2-propyl) phosphite;Tris[2,2,2-trifluoro-1-(trifluoromethyl)ethyl] phosphite;phosphorous acid tris(1,1,1,3,3,3-hexafluoropropan-2-yl) ester;2-Propanol, 1,1,1,3,3,3-hexafluoro-, 2,2',2''-phosphite;Phosphorous Acid Tris(1,1,1,3,3,3-hexafluoro-2-propyl) Ester
CAS:66470-81-3
MF:C9H3F18O3P
MW:532.06
EINECS:
Product Categories:
Mol File:66470-81-3.mol
TRIS(1,1,1,3,3,3-HEXAFLUORO-2-PROPYL) PHOSPHITE Structure
TRIS(1,1,1,3,3,3-HEXAFLUORO-2-PROPYL) PHOSPHITE Chemical Properties
Boiling point 130 °C (lit.)
density 1.69 g/mL at 25 °C (lit.)
refractive index n20/D 1.300(lit.)
form clear liquid
color Colorless to Almost colorless
BRN 2315565
Safety Information
Hazard Codes Xi
Risk Statements 36/37/38
Safety Statements 26-36
WGK Germany 3
HS Code 2920290090
MSDS Information
ProviderLanguage
SigmaAldrich English
TRIS(1,1,1,3,3,3-HEXAFLUORO-2-PROPYL) PHOSPHITE Usage And Synthesis
UsesTris(1,1,1,3,3,3-hexafluoro-2-propyl) Phosphite acts as a catalyst in combination with rhodium complex in the hydroformylation of olefins.
General DescriptionTris(1,1,1,3,3,3-hexafluoro-2-propyl) phosphite (tris(1,1,1,3,3,3-hexafluoroisopropyl) phosphite) is a sterically hindered, weakly σ-donating and strongly π-accepting ligand. It can be prepared by the reaction of lithium salt of 1,1,1,3,3,3-hexafluoro-2-propoxide with PCl3. It reacts with nucleosides to form deoxyribonucleoside 3′-bis(1,1,1,3,3,3-hexafluoro-2-propyl) phosphite units.
TRIS(1,1,1,3,3,3-HEXAFLUORO-2-PROPYL) PHOSPHITE Preparation Products And Raw materials
Raw materials3'-bis(1,1,1,3,3,3-hexafluoro-2-propyl)phosphite-->2-Propanol, 1,1,1,3,3,3-hexafluoro-, sodium salt-->1,1,1,3,3,3-Hexafluoro-2-propanol-->Triethylamine
TRIS(1,1,1,3,3,3-HEXAFLUORO-2-PROPYL) PHOSPHITE Diisopropyl phosphite Triisopropyl phosphite TRIS(2,2,2-TRIFLUOROETHYL) PHOSPHITE

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