ChemicalBook Product Catalog Chemical Reagents Organic reagents Thiol ester TRIS(METHYLTHIO)METHANE

TRIS(METHYLTHIO)METHANE

TRIS(METHYLTHIO)METHANE Basic information
Product Name:TRIS(METHYLTHIO)METHANE
Synonyms:3-METHYLTHIO-2,4-DITHIAPENTANE;TRIMETHYL TRITHIOORTHOFORMATE;TRI(METHYLTHIO)ORTHOFORMATE;TRIS(METHYLTHIO)METHANE;TRIS(METHYLTHIO)METHANE 98+%;Methyl orthotrithioformate;Orthoformic acid, trithio-, trimethyl ester;Tris(methylsulfanyl)methane
CAS:5418-86-0
MF:C4H10S3
MW:154.32
EINECS:
Product Categories:
Mol File:5418-86-0.mol
TRIS(METHYLTHIO)METHANE Structure
TRIS(METHYLTHIO)METHANE Chemical Properties
Melting point 16 °C (lit.)
Boiling point 102 °C/15 mmHg (lit.) 225-227 °C (lit.)
density 1.16 g/mL at 25 °C (lit.)
refractive index n20/D 1.577(lit.)
Fp 204 °F
form liquid
Odorat 0.10 % in propylene glycol. earthy mushroom musty truffle
Odor Typeearthy
BRN 1733825
LogP1.865 (est)
Safety Information
Hazard Codes Xi
Risk Statements 36/37/38
Safety Statements 26-36
RIDADR UN 2810 6.1/PG 3
WGK Germany 3
F 10-13-21
HS Code 29309099
MSDS Information
ProviderLanguage
SigmaAldrich English
ACROS English
TRIS(METHYLTHIO)METHANE Usage And Synthesis
Chemical Propertiesclear colorless to yellow liquid
UsesTris(methylthio)methane has been used in synthesis of:
  • (?)-nephrosteranic acid and (?)-roccellaric acid
  • (4R,5R)-5-({[1-(tert-butyl)-1,1-diphenylsilyl]oxy}methyl)4-[tri(methylthio)methyl]tetrahydro-furan-2-one
  • terminal difluoromethylenes
General DescriptionTris(methylthio)methane is a carboxylic anion equivalent.
TRIS(METHYLTHIO)METHANE Preparation Products And Raw materials
Preparation ProductsS,S'-Dimethyl dithiocarbonate-->N-HEXADECANE-D34
TRIS(ETHYLTHIO)METHANE TRIS(METHYLTHIO)METHANE TRIPHENYL TRITHIOORTHOFORMATE 2-(Methylthio)-1,3-benzodithiole AKOS 92614 1 2-DIMETHYL-3-PROPYLIMIDAZOLIUMTRIS(TRI
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