ChemicalBook Product Catalog Chemical Reagents Organic reagents Thiol ester S-TERT-BUTYL THIOACETATE

S-TERT-BUTYL THIOACETATE

S-TERT-BUTYL THIOACETATE Basic information
Product Name:S-TERT-BUTYL THIOACETATE
Synonyms:S-TERT-BUTYL THIOACETATE;Thioacetic acid S-(tert-butyl) ester;Thioacetic acid S-tert-butyl ester;CH3C(O)SC(CH3)3;Ethanethioic acid S-tert-butyl ester;S-(tert-Butyl) ethanethioate;S-tert-Butyl thioacetate 98%;Ethanethioic acid, S-(1,1-dimethylethyl) ester
CAS:999-90-6
MF:C6H12OS
MW:132.22
EINECS:
Product Categories:Sulfur Compounds;Thiol Esters;Organic Building Blocks;Sulfur Compounds;Thiol Esters;Building Blocks;Chemical Synthesis;Organic Building Blocks
Mol File:999-90-6.mol
S-TERT-BUTYL THIOACETATE Structure
S-TERT-BUTYL THIOACETATE Chemical Properties
Boiling point 135-136 °C (lit.)
density 0.927 g/mL at 25 °C (lit.)
refractive index n20/D 1.453(lit.)
Fp 93 °F
BRN 1740436
LogP2.133 (est)
Safety Information
Risk Statements 10
Safety Statements 23-24/25
RIDADR UN 1993 3/PG 3
WGK Germany 3
F 9-13
HazardClass 3.2
PackingGroup III
MSDS Information
ProviderLanguage
SigmaAldrich English
S-TERT-BUTYL THIOACETATE Usage And Synthesis
UsesS-tert-Butyl thioacetate may be used for the preparation of vinyloxyborane derivative.
General DescriptionS-tert-Butyl thioacetate is a thioester.
Purification MethodsDissolve it in CHCl3 (EtOH-free), wash with H2O, 10% H2SO4, saturated aqueous NaHCO3 (care CO2 liberated), H2O again, dry over Drierite and anhydrous K2CO3, and fractionate under reduced pressure. [Rylander & Tarbell J Am Chem Soc 72 3021 1950, Beilstein 2 IV 546.]
S-TERT-BUTYL THIOACETATE Preparation Products And Raw materials
5-(2-ETHYL-BUTYL)-4-HYDROXY-3,5-DIMETHYL-5H-THIOPHEN-2-ONE 8-ACETYLTHIOMENTHAN-3-ONE ETHYLDIPHENYLMETHYL THIOACETATE S-TERT-BUTYL ACETOTHIOACETATE S-TERT-BUTYL THIOACETATE 4-HYDROXY-5-HYDROXYMETHYL-3,5-DIMETHYL-5H-THIOPHEN-2-ONE 2-ACETYLTHIOISOBUTYRIC ACID 3-((Dimethylamino)methyl)-3-methylbenzo(c)thiophen-1(3H)-one hydrochlo ride 5-ALLYL-4-HYDROXY-3,5-DIMETHYL-5H-THIOPHEN-2-ONE TRIPHENYLMETHANETHIOL ACETATE S-(TERT-BUTYL) 2-([1-METHYL-5-(TRIFLUOROMETHYL)-1H-PYRAZOL-3-YL]OXY)ETHANETHIOATE 5-((E)-BUTA-1,3-DIENYL)-4-HYDROXY-3,5-DIMETHYL-5H-THIOPHEN-2-ONE THIOLACTOMYCIN 4-HYDROXY-3,5-DIMETHYL-5-(2-METHYL-ALLYL)-5H-THIOPHEN-2-ONE 1,4-Dimethyl bis-thiololactone thiotetromycin 5-CYCLOPENTYL-4-HYDROXY-3,5-DIMETHYL-5H-THIOPHEN-2-ONE 4-HYDROXY-5-ISOBUTYL-3,5-DIMETHYL-5H-THIOPHEN-2-ONE
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