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H-D-PHG-OME HCL

H-D-PHG-OME HCL Basic information
Product Name:H-D-PHG-OME HCL
Synonyms:Methyl α-aMinophenylacetate HCl;(2-keto-2-methoxy-1-phenyl-ethyl)ammonium chloride;(2-methoxy-2-oxo-1-phenylethyl)ammonium chloride;(2-methoxy-2-oxo-1-phenyl-ethyl)ammonium chloride;(2-methoxy-2-oxo-1-phenylethyl)azanium chloride;(2-methoxy-2-oxo-1-phenyl-ethyl)azanium chloride;methyl amino(phenyl)acetate hydrochloride;T0400-4069
CAS:19883-41-1
MF:C9H12ClNO2
MW:201.65
EINECS:243-399-9
Product Categories:Phenylglycine Derivatives;Peptide Synthesis;Unnatural Amino Acid Derivatives;Phenylglycine [Phg];Amino Acids
Mol File:19883-41-1.mol
H-D-PHG-OME HCL Structure
H-D-PHG-OME HCL Chemical Properties
Melting point 189-191 °C(lit.)
alpha -118o (C=1 IN H2O)
storage temp. Inert atmosphere,Room Temperature
solubility Soluble in Chloroform,Dichloromethane,Ethyl Acetate,DMSO,Acetone,etc.
form powder to crystal
color White to Almost white
optical activity[α]20/D 118°, c = 1 in H2O
BRN 3915654
InChIInChI=1/C9H11NO2.ClH/c1-12-9(11)8(10)7-5-3-2-4-6-7;/h2-6,8H,10H2,1H3;1H/t8-;/s3
InChIKeyDTHMTBUWTGVEFG-DDWIOCJRSA-N
SMILESC(OC)(=O)[C@H](C1=CC=CC=C1)N.[H]Cl |&1:4,r|
CAS DataBase Reference19883-41-1(CAS DataBase Reference)
Safety Information
Hazard Codes Xi
Risk Statements 36
Safety Statements 26-36/37
WGK Germany 3
HS Code 29224999
MSDS Information
ProviderLanguage
SigmaAldrich English
ALFA English
H-D-PHG-OME HCL Usage And Synthesis
Chemical PropertiesWhite solid
Uses(R)-(-)-2-Phenylglycine Methyl Ester Hydrochloride is an intermediate in the synthesis of Cephradine, a cephalosporin antibiotic. It functions as an acyl donor in the enzymatic synthetic process for cephradine synthesis.
H-D-PHG-OME HCL Preparation Products And Raw materials
Preparation Products1,4-Diazabicyclo[2.2.2]octane, 2-phenyl-, (2R)-
D-Phenylalanine, 2-fluoro-, methyl ester METHYL (2R)-2-AMINO-3-(2,4-DIFLUOROPHENYL)PROPANOATE METHYL (2R)-2-AMINO-3-(2,6-DICHLORO(3-PYRIDYL))PROPANOATE METHYL (2R)-2-AMINO-3-(2-CHLORO(4-PYRIDYL))PROPANOATE H-D-Phg-Gly-OH METHYL (2R)-2-AMINO-3-(2-CHLOROPHENYL)PROPANOATE METHYL (2R)-2-AMINO-3-(2,6-DIFLUOROPYRIDIN-3-YL)PROPANOATE H-D-PHG-OTBU HCL METHYL (2R)-2-AMINO-3-(2,3-DIFLUOROPHENYL)PROPANOATE METHYL (2R)-2-AMINO-3-(2,6-DIMETHYL(3-PYRIDYL))PROPANOATE methyl (R)-aminophenylacetate methyl (2R)-2-amino-3-(2-fluorophenyl)propanoate hydrochloride METHYL (2R)-2-AMINO-3-(2-CHLORO-4-HYDROXYPHENYL)PROPANOATE (R)-4-CHLORO PHENYLGLYCINE H-D-PHG-OME·HCL, L-PHENYLGLYCINE METHY ESTER HYDROCHLORIDE METHYL D-2-(4-FLUOROPHENYL)GLYCINATE HCL H-PHG-OME HCL H-PHG-OME HCL,H-L-Phg-OMe*HCl
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