Trichloromethanesulfonyl chloride

Trichloromethanesulfonyl chloride Basic information
Product Name:Trichloromethanesulfonyl chloride
Synonyms:TRICHLOROMETHANESULFONYL CHLORIDE;Trichlor-methansulfonylchlorid;trichloro-methanesulfonylchlorid;Trichloromesyl chloride.;TRICHLOROMETHANESULFONYL CHLORIDE, TECH.;trichloromethanesulphonyl chloride;Trichloromethanesulfonyl chloride,pract.;trichloromethanesulfonyl chloride CCl4O2S
CAS:2547-61-7
MF:CCl4O2S
MW:217.89
EINECS:219-830-1
Product Categories:Chlorination;Halogenation;Synthetic Organic Chemistry;Organic Building Blocks;Sulfonyl Halides;Sulfur Compounds;Building Blocks;Chemical Synthesis;Organic Building Blocks;Sulfonyl Halides;Sulfur Compounds
Mol File:2547-61-7.mol
Trichloromethanesulfonyl chloride Structure
Trichloromethanesulfonyl chloride Chemical Properties
Melting point 137-140 °C(lit.)
Boiling point 170°C
density 1.8252 (estimate)
solubility soluble in Toluene
form solid
color White to Almost white
CAS DataBase Reference2547-61-7(CAS DataBase Reference)
NIST Chemistry ReferenceMethanesulfonyl chloride, trichloro-(2547-61-7)
EPA Substance Registry SystemMethanesulfonyl chloride, trichloro- (2547-61-7)
Safety Information
Hazard Codes C
Risk Statements 34-36/37
Safety Statements 26-27-28-36/37/39-45
RIDADR UN 3261 8/PG 2
WGK Germany 3
HS Code 2904.10.5000
HazardClass 8
PackingGroup III
MSDS Information
ProviderLanguage
SigmaAldrich English
Trichloromethanesulfonyl chloride Usage And Synthesis
General DescriptionTrichloromethanesulfonyl chloride is an efficient free radical chlorinating agent. It reacts with pent-4-enylcobaloximes in inert solvent under tugsten lamp irradiation to yield 2-(β,β,β- trichloroethyl)sulfolanes. It also reacts with trimethylsilyl enol ethers of acetophenones in the presence of a ruthenium (II) phosphine complex to yield 1-aryl-3,3-dichloropropen-1-one and α-chloroacetophenones.
Trichloromethanesulfonyl chloride Preparation Products And Raw materials
Tri-tert-butyl 1,4,7,10-Tetraazacyclododecane-1,4,7-triacetate HydrobroMide Benzyl chloride Triphosgene Trichloromethanesulfonyl chloride Calcium chloride Chloromethanesulfonyl chloride Methyltrichlorosilane alpha-Toluenesulfonyl chloride Choline chloride Methanesulfonyl chloride Benzotrichloride DICHLOROMETHANESULFONYL CHLORIDE Ammonium chloride Perchloromethylmercaptan Mepiquat chloride 2-​[[(2-​ethylphenyl)​(2-​hydroxyethyl)​amino]​methyl]​-​3,​3-​difluoro-Propanenitrile TRICHLOROMETHANESULFINYL CHLORIDE 4-(Trifluoromethyl)benzene-1-sulfonyl chloride

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