(-)-BIS[(S)-1-PHENYLETHYL]AMINE HYDROCHLORIDE

(-)-BIS[(S)-1-PHENYLETHYL]AMINE HYDROCHLORIDE Basic information
Product Name:(-)-BIS[(S)-1-PHENYLETHYL]AMINE HYDROCHLORIDE
Synonyms:(-)-BIS[(S)-ALPHA-METHYLBENZYL]AMINE HYDROCHLORIDE;(-)-BIS[(S)-1-PHENYLETHYL]AMINE HYDROCHLORIDE;(S,S)-(-)-BIS(ALPHA-METHYLBENZYL)AMINE HYDROCHLORIDE;(S,S)-(-)-BIS(1-PHENYLETHYL)AMINE HYDROCHLORIDE;[S-(R*,R*)]-(-)-BIS(-ALPHA-METHYLBENZYL)AMINE HYDROCHLORIDE;(S,S)-(-)-Bis(α-methylbenzyl)amineHydrochloride;(-)-Bis[(S)-1-phenylethyl]amineHCl;(-)-bis[(s)-α-methylbenzyl]amine hydrochloride
CAS:40648-92-8
MF:C16H20ClN
MW:261.79
EINECS:
Product Categories:chiral;Asymmetric Synthesis;Synthetic Organic Chemistry
Mol File:40648-92-8.mol
(-)-BIS[(S)-1-PHENYLETHYL]AMINE HYDROCHLORIDE Structure
(-)-BIS[(S)-1-PHENYLETHYL]AMINE HYDROCHLORIDE Chemical Properties
Melting point 261-263 °C(lit.)
refractive index -73 ° (C=3, EtOH)
storage temp. Inert atmosphere,Room Temperature
form powder to crystal
color White to Almost white
optical activity[α]20/D 73±2°, c = 3% in ethanol
BRN 4723969
Safety Information
Hazard Codes Xi,Xn
Risk Statements 36/37/38-22
Safety Statements 26-36-36/37/39
WGK Germany 3
3
HS Code 2921.49.5000
MSDS Information
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ACROS English
SigmaAldrich English
(-)-BIS[(S)-1-PHENYLETHYL]AMINE HYDROCHLORIDE Usage And Synthesis
Chemical Propertieswhite to light yellow crystal powde
Uses(?)-Bis[(S)-1-phenylethyl]amine hydrochloride can be used:
  • To prepare phosphoramidite (Feringa) ligand named (R)-2,2′-binaphthoyl-(S,S)-di-(1-phenylethyl)aminoylphosphine.
  • As a chiral amphiphilic cation to encapsulate polyoxometalates, which act as supramolecular assemblies employed in the asymmetric oxidation of sulfides.
  • As a chiral shift agent in the determination of enantiomeric purity of tris(tetrachlorobenzenediolato) phosphate(V) anion using 31P NMR.

(-)-BIS[(S)-1-PHENYLETHYL]AMINE HYDROCHLORIDE Preparation Products And Raw materials
Raw materialsEthyl acetate-->Tetrahydrofuran-->Dichloromethane-->Palladium-->Sodium borohydride-->Di-tert-butyl dicarbonate-->Acetophenone-->L-1-Phenylethylamine
(S)-(-)-N-Benzyl-1-phenylethylamine (R)-(+)-N,N-DIMETHYL-1-PHENYLETHYLAMINE (S)-(-)-1-(2-Naphthyl)ethylamine (R)-(+)-1-(1-Naphthyl)ethylamine N-BENZYLCINCHONINIUM CHLORIDE N-Benzylcinchonidinium chloride (S)-(-)-1-(1-Naphthyl)ethylamine (S)-(-)-1-(P-TOLYL)ETHYLAMINE (S)-(-)-N,N-DIMETHYL-1-PHENETHYLAMINE (+)-BIS[(R)-1-PHENYLETHYL]AMINE HYDROCHLORIDE (R)-(+)-1-(1-Naphthyl)ethylamine hydrochloride (R)-(+)-1-(2-NAPHTHYL)ETHYLAMINE PAVINE HCL ESCHSCHOLTZINE HCL (+)-BIS[(R)-1-PHENYLETHYL]AMINE HYDROCHLORIDE (-)-BIS[(S)-1-PHENYLETHYL]AMINE HYDROCHLORIDE CALIFORNIDINE PERCHLORATE BIS((S)-1-(1-NAPHTHYL) ETHYL)AMINE HYDROCHLORIDE

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