ChemicalBook Product Catalog Organic Chemistry Amides Naphthenic amines derivatives 3-Bromo-2-methylaniline

3-Bromo-2-methylaniline

3-Bromo-2-methylaniline Basic information
Application
Product Name:3-Bromo-2-methylaniline
Synonyms:3-Bromo-2-methylanilin;3-BROMO-2-METHYLANILINE, 98+%;3-Bromo-2-toluidine;3-Bromo-2-methylanil;3-BroMo-2-Methylanilline;3-BroMo-2-Methylaniline , 98.0%(GC&T;2-Amino-6-bromotoluene~3-Bromo-o-toluidine;3-bromo-o-toluidine
CAS:55289-36-6
MF:C7H8BrN
MW:186.05
EINECS:259-568-5
Product Categories:Amines;C7;Nitrogen Compounds;Miscellaneous;Anilines, Amides & Amines;Bromine Compounds;Aromatic Hydrocarbons (substituted) & Derivatives
Mol File:55289-36-6.mol
3-Bromo-2-methylaniline Structure
3-Bromo-2-methylaniline Chemical Properties
Boiling point 248 °C (lit.)
density 1.51 g/mL at 25 °C (lit.)
refractive index n20/D 1.619(lit.)
Fp 230 °F
storage temp. Keep in dark place,Inert atmosphere,Room temperature
pka3.38±0.10(Predicted)
form Liquid
color Clear colorless to yellow to pale brown
Sensitive Light Sensitive
BRN 2354213
InChIKeyIILVSKMKMOJHMA-UHFFFAOYSA-N
CAS DataBase Reference55289-36-6(CAS DataBase Reference)
NIST Chemistry Reference3-Bromo-2-methylaniline(55289-36-6)
Safety Information
Hazard Codes Xi
Risk Statements 36/37/38
Safety Statements 26-36
RIDADR 2810
WGK Germany 3
Hazard Note Harmful/Irritant
HazardClass 6.1
PackingGroup III
HS Code 29214300
MSDS Information
ProviderLanguage
2-Amino-6-bromotoluene English
SigmaAldrich English
ALFA English
3-Bromo-2-methylaniline Usage And Synthesis
Application

3-Bromo-2-methylaniline is a 3-halo-2-methylaniline derivative. 3-bromo-2-methylaniline is an important organic intermediate (building block) to synthetize substituted aniline products. 3-Bromo-2-methylaniline may be used in the preparation of 3,4-dibromo-2-methylaniline, racemic 3,9-dibromo-4,10-dimethyl-6H,12H,5,11-methanodibenzodiazocine, a racemic derivative of Tröger’s base, 4-bromo-1H-indazole, and so on.

Chemical PropertiesColorless to pale brown liquid
Uses3-Bromo-2-methylaniline may be used in the preparation of :
  • 3,4-dibromo-2-methylaniline
  • racemic 3,9-dibromo-4,10-dimethyl-6H,12H,5,11-methanodibenzodiazocine, a racemic derivative of Tr?ger′s base
  • 4-bromo-1H-indazole
General Description3-Bromo-2-methylaniline is a 3-halo-2-methylaniline derivative.
3-Bromo-2-methylaniline Preparation Products And Raw materials
Preparation Products2-amino-4-bromo-3-methylbenzoic acid-->3-Amino-2-methylphenylboronic acid, pinacol ester-->4-broMo-3-Methylbenzene-1,2-diaMine-->4-BROMO-1-METHYL-1H-INDAZOLE-->1H-indazole-4-carbonitrile-->6-Bromoisatinic anhydride-->4-(4,4,5,5-TETRAMETHYL-[1,3,2]DIOXABOROLAN-2-YL)-1H-INDAZOLE-->2,6-DIBROMOBENZALDEHYDE-->2-Bromo-6-fluorobenzoic acid-->Indazole-->N-(3-Bromo-2-methyl-6-nitrophenyl)-2,2,2-trifluoroacetamide-->AcetaMide, N-(3-broMo-2-Methylphenyl)-
3-Bromo-2-methylaniline, HCl N-[1-(1,3-benzothiazol-2-yl)ethyl]-2-bromo-4-methylaniline N-(1H-1,2,3-BENZOTRIAZOL-1-YLMETHYL)-4-BROMO-3-METHYLANILINE 2-BROMO-4-METHYLANILINE HYDROCHLORIDE,2-BROMO-4-METHYLANILINE HCL,2-BROMO-4-METHYLANILINE HYDROCHLORIDE 97% 4-Bromo-3-methylaniline hydrochloride 4-Bromo-5-methyl-2,3-indolinedione 2,4-Dibromo-6-methylaniline 4-BROMO-3-METHYLANILINE HYDROCHLORIDE,4-BROMO-3-METHYLANILINE HCL 3,3',5,5'-Tetramethylbenzidine dihydrochloride EC 2.6.1.2 N-(TERT-BUTOXYCARBONYL)-4-BROMO-2-METHYLANILINE ALTRENOGEST N-(1-benzofuran-2-ylmethyl)-2-bromo-4-methylaniline 4-BROMO-O-TOLUIDINE (NH2=1) = 4-BROMO-2-METHYLANILINE 2-BROMO-4-METHYLANILINE, (4-AMINO-3-BROMOTOLUENE; 2-BROMO-P-TOLUIDINE) AMINO ACIDS 3-Bromo-5-methylaniline, HCl 2-BROMO-3-METHYL-4-NITROPHENOL
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