Glyoxylic acid monohydrate

Glyoxylic acid monohydrate Basic information
Product Name:Glyoxylic acid monohydrate
Synonyms:Formylformic acid, Oxoethanoic acid;Glyoxylic acid monohydrate, 98%, pure;Glyoxylic acid monoh;Oxoacetic Acid Monohydrate,50%;Glyoxylic acid Monohydrate, pure, 98% 25GR;Glyoxylic acid Monohydrate, pure, 98% 500GR;2-Oxoacetic Acid Monohydrate;NSC 27785 Monohydrate
CAS:563-96-2
MF:C2H4O4
MW:92.05
EINECS:679-230-4
Product Categories:Fine chemical;Aliphatics;563-96-2
Mol File:563-96-2.mol
Glyoxylic acid monohydrate Structure
Glyoxylic acid monohydrate Chemical Properties
Melting point 49-52 °C(lit.)
Boiling point 100 °C(lit.)
density 1.33 g/mL at 20 °C
refractive index n20/D 1.414
Fp >230 °F
storage temp. Store below +30°C.
solubility H2O: 0.1 g/mL, clear
pka3.43±0.11(Predicted)
form Liquid
color White to light yellow
Water Solubility Freely soluble
Sensitive Hygroscopic
Merck 14,4511
BRN 969535
InChIKeyMOOYVEVEDVVKGD-UHFFFAOYSA-N
CAS DataBase Reference563-96-2(CAS DataBase Reference)
Safety Information
Hazard Codes C,Xi
Risk Statements 34-43-41
Safety Statements 26-36/37/39-45-37/39-24-27
RIDADR UN 3265 8/PG 2
WGK Germany 1
RTECS MD4550000
3
TSCA Yes
HazardClass 8
PackingGroup III
HS Code 29183000
MSDS Information
ProviderLanguage
ACROS English
SigmaAldrich English
ALFA English
Glyoxylic acid monohydrate Usage And Synthesis
Chemical Propertieswhite to light yellow crystalline powder or chunks
UsesGlyoxylic acid is a reagent for sulfinylmaleate synthesis. It is one of the chemicals used in the Hopkins Cole reaction. It is involved to check the presence of tryptophan in proteins. It is condensed with urea and 1,2-diaminobenzene to form heterocycles. It also undergoes Friedel-Crafts and cyclocondensation reactions to form bis(pentamethylphenyl) acetic acid and a beta-carboline respectively. It is employed in the synthesis of a sulfinylmaleate, which serves as an efficient dienophile for enantioselective Diels-Alder cycloadditions.
UsesOccurs in unripe fruit and in young green leaves; has also been found in very young sugar beets.
Glyoxylic acid monohydrate Preparation Products And Raw materials
Preparation Products1,2,3,4-TETRAHYDRO-9H-PYRIDO[3,4-B]INDOLE-->1-Benzyl-5-ethoxyhydantoin
Ethylboronic acid (1R)-(-)-Menthyl glyoxylate hydrate Ethyl glyoxalate Methyl 2-oxoacetate SODIUM ETHANETHIOLATE Ethanethiol Sodium carboxyl methylstarch (1R,2S,5R)-5-Methyl-2-(1-methylethyl)cyclohexyl dihydroxy-acetate Glyoxylic acid monohydrate sodium salt, Oxoethanoic acid sodium salt MELIBIOSE 3,5-Dihdyroxyphenylacetic acid Methyl glycolate Ethyl 2-(Chlorosulfonyl)acetate Glyoxylic acid monohydrate Ascoric Acid Citric acid monohydrate Butyl hydroxyacetate 2-(2-Aminothiazol-4-yl)glyoxylic acid

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