3,5-DICHLOROPHENYLMAGNESIUM BROMIDE

3,5-DICHLOROPHENYLMAGNESIUM BROMIDE Basic information
Product Name:3,5-DICHLOROPHENYLMAGNESIUM BROMIDE
Synonyms:3,5-Dichlorophenylmagnesium bromide solution 0.5 in THF;3,5-DichlorophenylMagnesiuM broMide, 0.50 M solution in 2-Methyltetrahydrofuran;3,5-Dichlorophenylmagnesium bromide, 0.5M solution in THF, AcroSeal;3,5-DichlorophenylMagnesiuM broMide, 0.50M in 2-MeTHF;3,5-Dichlorophenylmagnesium bromide solution 0.5 M in THF;bromo(3,5-dichlorophenyl)magnesium;3,5-Dichlorophenylmagnesium bromide, 0.50 M in THF;magnesium,1,3-dichlorobenzene-5-ide,bromide
CAS:82297-90-3
MF:C6H3BrCl2Mg
MW:250.2
EINECS:
Product Categories:Grignard Reagent;Aryl;Grignard Reagents;Organometallic Reagents
Mol File:82297-90-3.mol
3,5-DICHLOROPHENYLMAGNESIUM BROMIDE Structure
3,5-DICHLOROPHENYLMAGNESIUM BROMIDE Chemical Properties
Boiling point 65 °C
density 0.972 g/mL at 25 °C
Fp 1 °F
storage temp. 2-8°C
form Liquid
color Brown to black
Safety Information
Hazard Codes F,C,F+
Risk Statements 11-14-19-22-34-40-12-37
Safety Statements 16-23-26-36/37/39-45
RIDADR UN 2924 3/PG 2
WGK Germany 1
HS Code 29310099
MSDS Information
ProviderLanguage
SigmaAldrich English
3,5-DICHLOROPHENYLMAGNESIUM BROMIDE Usage And Synthesis
Uses3,5-Dichlorophenylmagnesium bromide can be used:
  • In one of the key synthetic steps for the preparation of non-alternant polycyclic hydrocarbon named indeno-benzophenalene.
  • As a substrate in the synthesis of carboxylic esters by reacting with 2-methyl-4,6-pyrimidyl dicarbonates.
  • As a substrate in the synthesis of aryl ketones by reacting with acid chlorides using bis[2-(N,N-dimethylamino)ethyl] ether ligand.

3,5-DICHLOROPHENYLMAGNESIUM BROMIDE Preparation Products And Raw materials
Raw materials1-Bromo-3,5-dichlorobenzene
Preparation Products(R)-A,A-BIS(3,5-DICHLOROPHENYL)-2-PYRROLIDINEMETHANOL HYDROCHLORIDE
3,5-DIFLUOROPHENYLMAGNESIUM BROMIDE PHENYLMAGNESIUM BROMIDE 4-N-PROPYLPHENYLMAGNESIUM BROMIDE BENZYLMAGNESIUM BROMIDE 3,4-DIMETHOXYPHENYLMAGNESIUM BROMIDE 4-FLUOROPHENYLMAGNESIUM BROMIDE 3,5-DIMETHOXYBENZYL BROMIDE 3,4-DIFLUOROPHENYLMAGNESIUM BROMIDE 4-CHLOROPHENYLMAGNESIUM BROMIDE 3 5-DIMETHYOXYPHENYLMAGNESIUM CHLORIDE 3 4 5-TRIFLUOROPHENYLMAGNESIUM BROMIDE 4-PHENOXYPHENYLMAGNESIUM BROMIDE 3,5-DIMETHOXYPHENYLMAGNESIUM BROMIDE 3,4-DICHLOROPHENYLMAGNESIUM BROMIDE 3-BUTENYLMAGNESIUM BROMIDE HEXYLMAGNESIUM BROMIDE 3-CHLOROPHENYLMAGNESIUM BROMIDE 3,5-DICHLOROPHENYLMAGNESIUM BROMIDE

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