4,4',4''-Tris(carbazol-9-yl)-triphenylamine

4,4',4''-Tris(carbazol-9-yl)-triphenylamine Basic information
Applications
Product Name:4,4',4''-Tris(carbazol-9-yl)-triphenylamine
Synonyms:4,4',4''-TRIS(CARBAZOL-9-YL)TRIPHENYLAMINE;TCATA;Tris[4-(carbazol-9-yl)phenyl]amine;TcTa;Tris(4-carbazoyl-9-ylphenyl)amine;4,4',4''-Tri-9-carbazolyltriphenylamine;TCTA,4,4',4''-Tris(carbazol-9-yl)-triphenylaMine;tris(4-(9H-carbazol-9-yl)phenyl)amine
CAS:139092-78-7
MF:C54H36N4
MW:740.89
EINECS:625-738-6
Product Categories:OLED materials,pharm chemical,electronic;oled materials;electronic;Electronic Chemicals;White powder
Mol File:139092-78-7.mol
4,4',4''-Tris(carbazol-9-yl)-triphenylamine Structure
4,4',4''-Tris(carbazol-9-yl)-triphenylamine Chemical Properties
Melting point 298~300°C
density 1.23±0.1 g/cm3(Predicted)
storage temp. Inert atmosphere,Room Temperature
pka-5.97±0.60(Predicted)
form powder to crystal
color White to Orange to Green
λmax326nm(CH2Cl2)(lit.)
InChIKeyAWXGSYPUMWKTBR-UHFFFAOYSA-N
CAS DataBase Reference139092-78-7
Absorptionλmax?293?and?326 nm (THF)
Safety Information
Hazard Codes Xi
Risk Statements 36/37/38
Safety Statements 26-36/37-36
WGK Germany 3
HS Code 29339900
MSDS Information
4,4',4''-Tris(carbazol-9-yl)-triphenylamine Usage And Synthesis
ApplicationsHaving three carbazole units as the pendants and triarylamine at the core, tris(4-carbazoyl-9-ylphenyl)amine (TCTA) is electron-rich. As a result, it is widely used as a hole-transport and hole-injection material in light-emitting diodes and perovskite solar cells. With low electron mobility, TCTA has also been used as exciton/electron blocking layer materials because of its high lying LUMO energy level (LUMO = 2.4 eV).
TCTA is also a very popular phosphorescent host material due to its large band gap (Eg = 3.4 eV) for green, red and white phosphorescent organic light-emitting diodes (PhOLEDs).
DescriptionHaving three carbazole units as the pendants and triarylamine at the core,?tris(4-carbazoyl-9-ylphenyl)amine (TCTA) is electron-rich. As a result, it is widely used as a hole-transport and hole-injection material in light-emitting diodes and perovskite solar cells. With low electron mobility, TCTA has also been used as exciton/electron blocking layer materials because of its high lying LUMO energy level (LUMO = 2.4 eV).
Chemical PropertiesLight yellow solid
Uses4,4'',4''''-Tris(carbazol-9-yl)-triphenylamine has been patented for use in the preparation of light-emitting materials for organic electroluminescent devices.
4,4',4''-Tris(carbazol-9-yl)-triphenylamine Preparation Products And Raw materials
4,4'-Bis(2,2-diphenylvinyl)-1,1'-biphenyl 4,4'-Bis(N-carbazolyl)-1,1'-biphenyl 8-Hydroxyquinoline aluminum salt 9,9'-Bianthracene 9-[3-(Dibenzo[b,d]furan-2-yl)phenyl]-9H-carbazole CZBDF POLY(N-VINYLCARBAZOLE) 3,3''-Di(9H-carbazol-9-yl)-1,1':3',1''-terphenyl 9,9-bis[4-(pyrenyl)phenyl]-9H-fluorene MADN , 2-Methyl-9,10-bis(naphthalen-2-yl)anthracene 9,10-BIS(4-METHOXYPHENYL)ANTHRACENE 9,10-Di(2-naphthyl)anthracene 1,3,5-Tri(9-carbazolyl)benzene 2,6-bis(3-(9H-carbazol-9-yl)phenyl)pyridine TAPA 4,4',4''-Tris(carbazol-9-yl)-triphenylamine Carbazole Triphenylamine

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