Chlorobis(cyclooctene)rhodium(I) dimer Usage And Synthesis
Chemical Properties
orange-brown powder
Uses
Chlorobis(cyclooctene)rhodium(I),dimer can be used as a catalyst:
To synthesize enantioenriched gem-diaryl sulfonates by asymmetric 1,4-addition of aryl boronic acids to α,β-unsaturated sulfonyl compounds.
In direct C-arylation of N-unprotected indoles and pyrroles.
In the carboxylation of arenes via C-H bond activation.
Uses
Chlorobis(cyclooctene)rhodium(I) dimer is an organometallic complex used as a catalyst in the arylzincation of alkynes. It is also used as a building block for other Rh-based catalysts, such as the preparation of rhodium bis(phosphinimine)pyrrole pincer carbonyl complexes for deoxygenative metathesis of CO.
Chlorobis(cyclooctene)rhodium(I) dimer Preparation Products And Raw materials