Chlorobis(cyclooctene)rhodium(I) dimer

Chlorobis(cyclooctene)rhodium(I) dimer Basic information
Product Name:Chlorobis(cyclooctene)rhodium(I) dimer
Synonyms:[RhCl(cis-cyclooctene)2]2;CHLOROBIS(CYCLOOCTENE)RHODIUM(I) DIMER;Chlorobis(cyclooctene)rhodium(I);Chlorobis(cyclooctene)rhodium(I)dimere;Chlorobis(cyclooctene)rhodium(I)dimer,min.98%;Chlorobis(cyclooctene)rhodium(I) dimer, min. 98%;Chlorobis(cyclooctene)rhodium(I) dimer,98%;CHLOROBIS(CYCLOOCTENE)RHODIUM()DIMER
CAS:12279-09-3
MF:C32H56Cl2Rh2
MW:717.5
EINECS:623-340-7
Product Categories:Rh;organometallic complex;Catalysts for Organic Synthesis;Classes of Metal Compounds;Homogeneous Catalysts;Metal Complexes;Rh (Rhodium) Compounds;Synthetic Organic Chemistry;Transition Metal Compounds;Catalysis and Inorganic Chemistry;Chemical Synthesis;Rhodium
Mol File:12279-09-3.mol
Chlorobis(cyclooctene)rhodium(I) dimer Structure
Chlorobis(cyclooctene)rhodium(I) dimer Chemical Properties
Melting point 190 °C (dec.) (lit.)
storage temp. Freezer
form crystal
color orange to red
Sensitive air sensitive, store cold
CAS DataBase Reference12279-09-3
Safety Information
Hazard Codes Xn
Risk Statements 20/21/22-36/37/38
Safety Statements 26-37/39
WGK Germany 3
TSCA No
HS Code 28439000
MSDS Information
ProviderLanguage
ACROS English
SigmaAldrich English
Chlorobis(cyclooctene)rhodium(I) dimer Usage And Synthesis
Chemical Propertiesorange-brown powder
UsesChlorobis(cyclooctene)rhodium(I),dimer can be used as a catalyst:
  • To synthesize enantioenriched gem-diaryl sulfonates by asymmetric 1,4-addition of aryl boronic acids to α,β-unsaturated sulfonyl compounds.
  • In direct C-arylation of N-unprotected indoles and pyrroles.
  • In the carboxylation of arenes via C-H bond activation.

UsesChlorobis(cyclooctene)rhodium(I) dimer is an organometallic complex used as a catalyst in the arylzincation of alkynes. It is also used as a building block for other Rh-based catalysts, such as the preparation of rhodium bis(phosphinimine)pyrrole pincer carbonyl complexes for deoxygenative metathesis of CO.
Chlorobis(cyclooctene)rhodium(I) dimer Preparation Products And Raw materials
BIS(NORBORNADIENE)RHODIUM (I) TETRAFLUOROBORATE Chlorobis(ethylene)rhodium (I) dimer Acetylacetonatobis(ethylene)rhodium(I) methoxy(cyclooctadiene)rhodium(i) dimer POLYALUMINUM CHLORIDE ALKYLKETENE DIMER Chlorinated polyethylene water-proof rolled materials Chlorobis(cyclooctene)rhodium(I) dimer POLYETHYLENE, CHLORINATED cis-Cyclooctene Rhodium(III) Chloride CYCLOOCTENE Rhodium DILINOLEIC ACID

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