3-(1-Pyridinio)-1-propanesulfonate

3-(1-Pyridinio)-1-propanesulfonate Basic information
Uses
Product Name:3-(1-Pyridinio)-1-propanesulfonate
Synonyms:NDSB-201;PPS;PYRIDINIUM N-PROPYL SULFOBETAINE;3-(1-PYRIDINIO)-1-PROPANESULFONATE;3-(1-PYRIDINIO)-1-PROPANESULFONATE INNER SALT;3-(1-PYRIDINIO)PROPANESULFONATE;3-(1-PYRIDINO)-1-PROPANE SULFONATE;1-(3-SULFOPROPYL)PYRIDINIUM BETAIN
CAS:15471-17-7
MF:C8H11NO3S
MW:201.24
EINECS:239-491-3
Product Categories:Detergents;Pyridinium Compounds;Sulfobetaines;15471-17-7
Mol File:15471-17-7.mol
3-(1-Pyridinio)-1-propanesulfonate Structure
3-(1-Pyridinio)-1-propanesulfonate Chemical Properties
Melting point 275-277 °C
density 1.53[at 20℃]
vapor pressure 0Pa at 25℃
Fp 160 °C
storage temp. Sealed in dry,Room Temperature
solubility Methanol (Slightly), Water (Slightly)
form White powder
color White
Water Solubility 240.5g/L at 25℃
BRN 1621867
InChIInChI=1S/C8H11NO3S/c10-13(11,12)8-4-7-9-5-2-1-3-6-9/h1-3,5-6H,4,7-8H2
InChIKeyREEBJQTUIJTGAL-UHFFFAOYSA-N
SMILESC1C=CC=C[N+]=1CCCS([O-])(=O)=O
LogP-2.78 at 21.5℃
CAS DataBase Reference15471-17-7
EPA Substance Registry SystemPyridinium, 1-(3-sulfopropyl)-, inner salt (15471-17-7)
Safety Information
Risk Statements 36/37/38
Safety Statements 26-24/25-22
WGK Germany 3
HS Code 29333990
MSDS Information
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SigmaAldrich English
3-(1-Pyridinio)-1-propanesulfonate Usage And Synthesis
Uses

Pyridinium propyl sulfobetaine can be used:

  • As a Bronsted acid ionic liquid catalyst in combination with H2SO4 and H3PO4 for the dehydration of glycerol to acrolein via semi-batch reaction technique.
  • As a catalyst in the form of sulfonated heteropoly acid salts for the synthesis of isoamyl isovalerate.
  • In the preparation of molybdenum imido alkylidene NHC catalysts, which are used in biphasic olefin metathesis.
  • To prepare water-stable SO3H-functionalized Brønsted acidic task-specific ionic liquids (TSILs).
  • In was bright nickel plating, it is a start material to make brightener, A high efficiency brightener and leveler. Because of its high purity, Pyridinium propyl sulfobetaine cannot carry other harmful impurity or salts to baths. 
Description3-(1-Pyridinio)-1-propanesulfonate is a white crystalline powder used to prepare electroplating additives.It has good thermal qualitative and chemical stability, and its mechanical strength is also very good. The low polymer molecular weight is prone to disproportionation and cross-linking reactions.
Chemical PropertiesWhite to Off-White Solid.
Uses3-(1-Pyridinio)-1-propanesulfonate can be used:
  • As a Bronsted acid ionic liquid catalyst in combination with H2SO4 and H3PO4 for the dehydration of glycerol to acrolein via semi-batch reaction technique.
  • As a catalyst in the form of sulfonated heteropoly acid salts for the synthesis of isoamyl isovalerate.
  • In the preparation of molybdenum imido alkylidene NHC catalysts, which are used in biphasic olefin metathesis.
  • To prepare water-stable SO3H-functionalized Br?nsted acidic task-specific ionic liquids (TSILs).
Uses3-(1-Pyridinio)-1-propanesulfonate is a non detergent sulfobetaine used as a mild solubilizing and stabilizing agent for halophilic malate dehydrogenase, halophilic elongation factor Tu (hTu), pig heart malate dehydrogenase, chicken egg w hite lysozyme and E. coli beta-galactosidase. Preserves the antigenic conformation of serine protease gp76. Does not interfere with colorimetric assays using p-nitrophenylphosphate and o-nitrophenyl -b-D-galactopyranoside as substrates. Reduces aggregation and significantly improves protein renaturation. Zwitterionic over a wide pH range. Does not absorb significantly in the near-UV range. Ca n be easily removed by dialysis.
UsesStronger leveling agent in nickel electroplating
Application3-(1-Pyridinio)-1-propanesulfonate is used in the preparation of electroplating additives,and it is used in medicine and daily chemicals.
SynthesisIn the equipped with a stirrer, thermometer, Calcium chloride drying tube and dropping funnelNecked flask was charged with 6.10g (0.05 mol)1,3-propanesultone and 150 mL of ethyl acetate was added and stirred until 1,3-propanesultone was dissolved. The flask was heated to 60°C in an oil bath equipped with methyl silicone oil. A solution of 5.14 g (0.065 mol) of pyridine was slowly added dropwise 50 mL of ethyl acetate, after the completion of the dropwise addition (dropwise time: 30 min)Insulation reaction 2h, pressure filtration, the residue was washed with ethyl acetate, vacuum drying, to give 3-(1-Pyridinio)-1-propanesulfonate 8.64 g. The yield was 86.0%.
3-(1-Pyridinio)-1-propanesulfonate Preparation Products And Raw materials
Raw materialsAzoniabenzene-->Pyridine-->1,3-Propane sultone
Pyridine hydrochloride Lignin Sulfonate Ammonium hydroxide 3-(1-Pyridinio)-1-propanesulfonate Hydroxide Sulfonates Pyridinium chlorochromate 1-(2-Hydroxy-3-sulfopropyl)-pyridinium betane HT INNER SPARE PARTS / PIECES GL18,10,0MM PPS HT INNER SPARE PARTS / PIECES DE RECHANGE INTERIEURES H GL45,22,0MM PPS HT LABORATORY SCREW JOINTS GL25,2,0MM,SW27 PPS HT INNER SPARE PARTS / PIECES GL32,4,0MM PPS 6-PPS HT REPLACEMENT CAPS, CONICAL / C GL45,SCHLAUCH11-16MM,SW42 PPS Sodium hydroxide Aluminum hydroxide 8-CHLOROADENOSINE-3',5'-CYCLIC MONOPHOSPHOROTHIOATE, RP-ISOMER SODIUM SALT Calcium hydroxide

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