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| | TRIS(2,6-DIMETHOXYPHENYL)PHOSPHINE Basic information |
| Product Name: | TRIS(2,6-DIMETHOXYPHENYL)PHOSPHINE | | Synonyms: | TRIS(2,6-DIMETHOXYPHENYL)PHOSPHINE;TDMPP;Tris(2,6-dimethoxyphenly)phosphine;TRIS(2,6-DIMETHOXYPHENYL)PHOSPHINE 97+% HPLC;Tris(2,6-dimethoxyphenyl)phosphine, 97+%;Tris(2,6-diMethoxyphenyl)phosphine, 97+% 5GR;Tris(2,6-dimethoxyphenyl)phosphine 98%;Tris(2,6-dimethoxyphenyl)phosphine, min. 97% | | CAS: | 85417-41-0 | | MF: | C24H27O6P | | MW: | 442.44 | | EINECS: | | | Product Categories: | Ligand;Phosphine Ligands;Synthetic Organic Chemistry;Basic Phosphine LigandsCatalysis and Inorganic Chemistry;Catalysis and Inorganic Chemistry;Cross-Coupling;Phosphine Ligands;Phosphorus Compounds | | Mol File: | 85417-41-0.mol |  |
| | TRIS(2,6-DIMETHOXYPHENYL)PHOSPHINE Chemical Properties |
| Melting point | 145-147 °C(lit.) | | Boiling point | 566.4±50.0 °C(Predicted) | | storage temp. | Sealed in dry,Room Temperature | | solubility | very faint turbidity in hot Methanol | | form | Powder | | color | white to off-white | | Sensitive | air sensitive | | CAS DataBase Reference | 85417-41-0 |
| Hazard Codes | Xi | | Risk Statements | 36/37/38 | | Safety Statements | 26-37/39 | | WGK Germany | 3 | | TSCA | No | | HS Code | 29310099 |
| | TRIS(2,6-DIMETHOXYPHENYL)PHOSPHINE Usage And Synthesis |
| Chemical Properties | white to light yellow crystal powde | | Uses | Catalyst for:
- Preparation of chiral building blocks via hydroalkynylation reactions or ynolates
- Three-component aza-Morita-Baylis-Hillman reactions (aza-MBH)
- Atom-economic synthesis of nitrogen heterocycles and ynenoates from alkynes
- Oxycylizations of allendiols
- Enantioselective aldol reactions
- Pd-mediated cross-coupling, Pd- and Cu-mediated benzannulation reactions and copper-mediated dimerization reactions
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| | TRIS(2,6-DIMETHOXYPHENYL)PHOSPHINE Preparation Products And Raw materials |
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