EXO-3,6-EPOXY-1,2,3,6-TETRAHYDROPHTHALIC ANHYDRIDE

EXO-3,6-EPOXY-1,2,3,6-TETRAHYDROPHTHALIC ANHYDRIDE Basic information
Product Name:EXO-3,6-EPOXY-1,2,3,6-TETRAHYDROPHTHALIC ANHYDRIDE
Synonyms:EXO-7-OXABICYCLO[2.2.1]HEPTENE-2,3-DICARBOXYLIC ANHYDRIDE;EXO-7-OXABICYCLO[2.2.1]HEPT-5-ENE-2,3-DICARBOXYLIC ANHYDRIDE;EXO-3,6-EPOXY-1,2,3,6-TETRAHYDROPHTHALIC ANHYDRIDE;3a-alpha,4-beta,7-beta,7a-alpha-tetrahydro-4,7-epoxyisobenzofuran-1,3-dione;4,7-epoxyisobenzofuran-1,3-dione,3a,4,7,7a-tetrahydro-,(3a-alpha,4-beta,7-bet;7a-alpha)-;EXO-3,6-EPOXY-1,2,3,6-TETRAHYDROPHTHALIC ANHYDRIDE 98+%;EXO-3,6-EPOXY-1,2,3,6-TETRAHYDROPHTHALIC ANHYDRIDE 97%
CAS:6118-51-0
MF:C8H6O4
MW:166.13
EINECS:629-406-1
Product Categories:Epoxide Monomers;Monomers;Polymer Science;Norbornene Derivatives;Fluorenes, etc. (reagent for high-performance polymer research);Functional Materials;Reagent for High-Performance Polymer Research
Mol File:6118-51-0.mol
EXO-3,6-EPOXY-1,2,3,6-TETRAHYDROPHTHALIC ANHYDRIDE Structure
EXO-3,6-EPOXY-1,2,3,6-TETRAHYDROPHTHALIC ANHYDRIDE Chemical Properties
Melting point 118 °C (dec.)(lit.)
Boiling point 372.0±42.0 °C(Predicted)
density 1.540±0.06 g/cm3(Predicted)
storage temp. under inert gas (nitrogen or Argon) at 2-8°C
form powder to crystal
color White to Almost white
Water Solubility Hydrolyzes in water.
Sensitive Moisture Sensitive
BRN 10355
CAS DataBase Reference6118-51-0
Safety Information
Hazard Codes Xi
Risk Statements 36/37/38
Safety Statements 26-37/39
WGK Germany 3
RTECS KC9650000
10-21
TSCA Yes
HS Code 29322090
MSDS Information
ProviderLanguage
ACROS English
SigmaAldrich English
ALFA English
EXO-3,6-EPOXY-1,2,3,6-TETRAHYDROPHTHALIC ANHYDRIDE Usage And Synthesis
Chemical Propertieswhite crystalline powder or chunks
UsesIntermediate in a useful synthesis of 4,4-dialkyl-2-butenolides, based on reaction with two moles of Grignard reagent, followed by cycloreversion (elimination of furan) to release the double bond.
EXO-3,6-EPOXY-1,2,3,6-TETRAHYDROPHTHALIC ANHYDRIDE Preparation Products And Raw materials
Raw materialsMaleic anhydride-->Furan
cis-1,2,3,6-Tetrahydrophthalic anhydride (R)-Tetrahydro-3-furancarboxylic acid 1,2,3,6-Tetrahydrophthalic anhydride (R)-(+)-3-CYCLOHEXENECARBOXYLIC ACID EXO-3,6-EPOXY-1,2,3,6-TETRAHYDROPHTHALIC ANHYDRIDE TETRAHYDROFURAN-3-CARBOXALDEHYDE 98 (S)-Tetrahydro-3-furancarboxylic acid EXO-3,6-EPOXY-1,2,3,6-TETRAHYDROPHTHALIC ANHYDRIDE 3-ALLYLOXYPROPIONIC ACID TETRAHYDRO-3-FUROIC ACID NAPHTHENIC ACID 4,7-epoxy-3a,4,7,7a-tetrahydroisobenzofuran-1(3h)-one Norbornene 4,10-DIOXATRICYCLO[5.2.1.0(2,6)]DEC-8-ENE-3,5-DIONE

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